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Kuznetsov, A.M.1
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W. Haiss, H. van Zalinge, D. Bethell, D. J. Schiffrine, J. Ulstruo, R. Nichols, Faraday Discuss. 2005, 131, 253.
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Haiss, W.1
Van Zalinge, H.2
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Ulstruo, J.5
Nichols, R.6
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The notion of segments stands usually for the chain unit or a group of building blocks involved in a concerted fluctuation
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The notion of segments stands usually for the chain unit or a group of building blocks involved in a concerted fluctuation.
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14
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N. J. Tao, C. Z. Li, H. X. He, J. Electroanal. Chem. 2000, 492, 81.
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, pp. 81
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Tao, N.J.1
Li, C.Z.2
He, H.X.3
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X. Xiao, B. Xu, N. J. Tao, Angew. Chem. 2004, 116, 6274;
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, pp. 6274
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Xu, B.2
Tao, N.J.3
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R. N. Barnett, C. L. Cleveland, . U. Landman, E. Boone, S. Kanvah, G. B. Schuster, J. Phys. Chem. A 2003, 107, 3525.
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, pp. 3525
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Barnett, R.N.1
Cleveland, C.L.2
Landman, U.3
Boone, E.4
Kanvah, S.5
Schuster, G.B.6
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20
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The distribution of potential and charge within the tunneling gap was extensively studied in the problem of electron transfer through molecular wires {see for example, S. K. Pati, J. Chem. Phys. 2003, 118, 6529;
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Pati, S.K.1
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and ref. [4]}
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E. G. Emberley, G. Kirczenow, Ann. New York Acad. Sci. 2002, 960, 131; and ref. [4]}. These works dwelled on a potential distribution arising due to a large number of electrons flowing through the molecules with a feedback of the tunneling current on the potential distribution and vice versa. Nothing of this kind is considered herein as we concentrate on rare electrons affected by the potential established by the environment.
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, vol.960
, pp. 131
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Emberley, E.G.1
Kirczenow, G.2
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23
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0025488494
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A distribution of potential in electrolyte solution near the STM tip was considered by W. Schmickler, D. Henderson, J. Electroanal. Chem. 1990, 290, 283. They modelled the tip by a metallic sphere and calculated the potential distribution in the linearized Poisson-Boltzmann approximation; the tunnel current in a bridge-free gap was calculated with the use of the electron density functional theory. The approach herein is simpler and straightforward with respect to the quantities under calculation.
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, vol.290
, pp. 283
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Schmickler, W.1
Henderson, D.2
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24
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33646480534
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(Eds.: E. Gileadi, M. Urbakh), Wiley-VCH, Weinheim
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It is well known that these potentials are not measurable within the thermodynamic approach, but in principle they can be calculated from the data of kinetic experiments, for example, electron photoemission into solution. The recommended absolute scales of potentials exist, although retrieving these potentials is model-dependent and requires high accuracy of measurements. For an update on this classical problem see O. A. Petrii, G. A. Tsirlina in Encyclopaedia of Electrochemistry, Vol. 1 (Eds.: E. Gileadi, M. Urbakh), Wiley-VCH, Weinheim, 2002, p. 3.
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, vol.1
, pp. 3
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Petrii, O.A.1
Tsirlina, G.A.2
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25
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33646753495
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note
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0 are determined exclusively by the metal/electrolyte electron work functions of the corresponding electrodes. For the case of a vacuum gap, these are simply metal/vacuum work functions.
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