Investigations into the reactivity of organoelement gallium subhalides - Syntheses of bifunctional digallium carboxylate iodides possessing bridged Ga-Ga bonds and terminal iodine atoms

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2006, Pages 1817-1823

  Uhl, Werner ^a   El Hamdan, Abdelhakim ^a   Schindler, Klaus Peter ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Carboxylato ligands; Gallium; Metal metal bonds; Subhalides; Subvalent compounds

Indexed keywords

ATOMS; BINARY ALLOYS; CARBOXYLATION; CHEMICAL BONDS; GALLIUM COMPOUNDS; LIGANDS;

BI-FUNCTIONAL; CARBON ATOMS; CARBOXYLATO; CARBOXYLATO LIGANDS; GALLIUM ATOMS; IODINE ATOMS; METAL-METAL BONDS; SUBHALIDES; SUBVALENT COMPOUNDS; TRIMETHYLSILYL;

CHELATION;

EID: 33646576551     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200600069     Document Type: Article

References (50)

1. a) W. Uhl, A. Jantschak, J. Organomet. Chem. 1998, 555, 263;
2. b) W. Uhl, W. Miller, M. Layh, W. Schwarz, Angew. Chem. 1992, 104, 1378;
3. Angew. Chem. Int. Ed. Engl. 1992, 31, 1364.
4. a) W. Uhl, R. Graupner, M. Layh, U. Schütz, J. Organomet. Chem. 1995, 493, C1;
5. b) W. Uhl, A. Jantschak, W. Saak, M. Kaupp, R. Wartchow, Organometallics 1998, 17, 5009.
6. W. Uhl, S. Melle, Chem. Eur. J. 2001, 7, 4216.
7. W. Uhl, A. El-Hamdan, M. Prött, P. Spuhler, G. Frenking, Dalton Trans. 2003, 1360.
8. a) W. Uhl, A. El-Hamdan, G. Geiseler, K. Harms, Z. Anorg. Allg. Chem. 2004, 630, 821;
9. for a review see: b) W. Uhl, Adv. Organomet. Chem. 2004, 51, 53.
10. W. Uhl, S. Melle, G. Geiseler, K. Harms, Organometallics 2001, 20, 3355.
11. W. Uhl, F. Schmock, G. Geiseler, Z. Anorg. Allg. Chem. 2002, 628, 1963.
12. a) M. Kehrwald, W. Köstler, A. Rodig, G. Linti, T. Blank, N. Wiberg, Organometallics 2001, 20, 860;
13. b) C. Klemp, C. Üffing, E. Baum, H. Schnöckel, Z. Anorg. Allg. Chem. 2000, 626, 1787;
14. c) G. Linti, W. Köstler, Angew. Chem. 1996, 108, 593;
15. Angew. Chem. Int. Ed. Engl. 1996, 35, 550;
16. d) A. H. Cowley, A. Decken, C. A. Olazabal, J. Organomet. Chem. 1996, 534, 271;
17. e) N. Wiberg, T. Blank, M. Westerhausen, S. Schneiderbauer, H. Schnöckel, I. Krossing, A. Schnepf, Eur. J. Inorg. Chem. 2002, 351;
18. f) V. Lomeli, B. G. McBurnett, A. H. Cowley, J. Organomet. Chem. 1998, 562, 123.
19. a) N. J. Hardman, R. J. Wright, A. D. Philligs, P. P. Power, Angew. Chem. 2002, 114, 2966;
20. Angew. Chem. Int. Ed. 2002, 41, 2842;
21. b) N. J. Hardman, R. J. Wright, A. D. Phillips, P. P. Power, J. Am. Chem. Soc. 2003, 125, 2667.
22. W. Uhl, A. El-Hamdan, A. Lawerenz, Eur. J. Inorg. Chem. 2005, 1056.
23. W. Uhl, A. El-Hamdan, Eur. J.- Inorg. Chem. 2004, 969.
24. W. Uhl, A. El-Hamdan, Z. Anorg. Allg. Chem., in press.
25. a) W. Uhl, F. Schmock, W. Petz, Z. Naturforsch., Teil B 2003, 58, 385;
26. b) W. Uhl, A. El-Hamdan, W. Petz, G. Geiseler, K. Harms, Z. Naturforsch., Teil B 2004, 59, 789;
27. c) G. Linti, W. Köstler, Chem. Eur. J. 1998, 4, 942;
28. G. Linti, G. Li, H. Pritzkow, J. Organomet. Chem. 2001, 626, 82.
29. See for instance: a) H. Schmidbaur, R. Nowak, W. Bublak, P. Burkert, B. Huber, G. Müller, Z. Naturforsch., Teil B 1987, 42, 553;
30. b) W. Hönle, A. Simon, G. Gerlach, Naturforsch., Teil B 1987, 42, 546;
31. c) M. A. Khan, D. G. Tuck, Inorg. Chim. Acta 1985, 97, 73;
32. d) H. P. Beck, Z. Naturforsch., Teil B 1987, 42, 251.
33. W. Uhl, R. Graupner, I. Hahn, T. Spies, W. Frank, Eur. J. Inorg. Chem. 1998, 355.
34. W. Uhl, M. Benter, W. Saak, P. G. Jones, Z. Anorg. Allg. Chem. 1998, 624, 1622; cited references.
35. a) W. Uhl, I. Hahn, H. Reuter, Chem. Ber. 1996, 129, 1425;
36. b) W. Uhl, T. Spies, W. Saak, Eur. J. Inorg. Chem. 1998, 1661;
37. c) W. Uhl, T. Spies, R. Koch, J. Chem. Soc., Dalton Trans. 1999, 2385.
38. a) W. Uhl, M. Layh, T. Hildenbrand, J. Organomet. Chem. 1989, 364, 289;
39. b) R. J. Wehmschulte, K. Ruhlandt-Senge, M. M. Olmstead, H. Hope, B. E. Sturgeon, P. P. Power, Inorg. Chem. 1993, 32, 2983;
40. X. He, R. A. Bartlett, M. M. Olmstead, K. Ruhlandt-Senge, B. E. Sturgeon, P. P. Power, Angew. Chem. 1993, 105, 761;
41. Angew. Chem. Int. Ed. Engl. 1993, 32, 717;
42. d) R. D. Schluter, A. H. Cowley, D. A. Atwood, R. A. Jones, M. R. Bond, C. J. Carrano, J. Am. Chem. Soc. 1993, 115, 2070.
43. a) R. C. Crittendon, B. C. Beck, J. Su, X.-W. Li, G. H. Robinson, Organometallics 1999, 18, 156;
44. b) P. Jutzi, B. Neumann, G. Reumann, H. G. Stammler, Organometallics 1998, 17, 1305;
45. c) A. Schnepf, C. Doriat, E. Möllhausen, H. Schnöckel, Chem. Commun. 1997, 2111.
46. W. Uhl, L. Cuypers, K. Schüler, T. Spies, C. Strohmann, K. Lehmen, Z. Anorg. Allg. Chem. 2000, 626, 1526.
47. T. Hahn (Ed.), International Tables for Crystallography, Space-Group Symmetry, vol. A, Kluwer Academic Publishers, Dordrecht, Boston, London, 1989.
48. SHELXTL-Plus, REL. 4.2; for Siemens R3 Crystallographic Research Systems, Siemens Analytical X-ray Instruments Inc., Madison, USA, 1990;
49. G. M. Sheldrick, SHELXL-97, Program for the Refinement of Structures, University of Göttingen 1997.
50. CCDC-295626 (for 2), -2956127 (for 4), and -295628 (for 7) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.