Electrochemical preparation of barium chlorate from barium chloride

Industrial and Engineering Chemistry Research

Volumn 45, Issue 9, 2006, Pages 2923-2928

  Vasudevan, Subramanyan ^a   Mohan, Swaminathan ^a  

^a CENTRAL ELECTROCHEMICAL RESEARCH INSTITUTE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ANODES; BARIUM COMPOUNDS; CATHODES; ELECTROLYTES; ENERGY UTILIZATION; OXIDATION; PH EFFECTS; STAINLESS STEEL;

CATHODE CURRENT DENSITY; CURRENT EFFICIENCY; ELECTROCHEMICAL OXIDATIONS;

ELECTROCHEMISTRY;

ANODES; BARIUM COMPOUNDS; CATHODES; ELECTROCHEMISTRY; ELECTROLYTES; ENERGY UTILIZATION; OXIDATION; PH EFFECTS; STAINLESS STEEL;

EID: 33646515561     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie051018r     Document Type: Article

References (34)

1. Ibl, N.; Vogt, H. Comprehensive Treatise of Electrochemistry; Bockris, J. O'M., Conway, B. E., Yeager. E., Eds.; Plenum Press: New York, 1980; Vol. 2, pp 169-96.
2. Foerster, F. Elektrochemie Wasseriger Losungen, 3rd ed.; Barth: Leipzig, Germany, 1922; pp 130-142.
3. De Valera, V. On the Theory of Electrochemical Chlorate Formation. Trans. Faraday Soc. 1953, 49, 1338-1351.
4. De Valera, V. Anodic oxygen evolution in chlorate cell. Trans. Faraday Soc. 1964, 60, 1450-1456.
5. Ibl, N.; Landolt, D. On the mechanism of anodic chlorate formation in dilute NaCl solution. J. Electrochem. Soc. 1968, 115, 713-720.
6. Landolt, D.; Ibl, N. On the mechanism of anodic chlorate formation in concentrated NaCl solution. Electrochim. Acta 1970, 15, 1165-1183.
7. Jaksic, M. M. Mass transfer and optimization of faradic yields in a chlorate cell process. Electrochim. Acta 1976, 21, 1127-36.
8. Jaksic, M. M. Mutual effect of current density, pH, temperature and hydrodynamic factors on current efficiency in the chlorate cell process. J. Electrochem. Soc. 1974, 121, 70-79.
9. Nechiporenko, N. N.; Voroshilov, P. Kh.; Sivokon, N. V.; Beidin, V. K. Investigation of the anode process in electrolysis of sodium chloride solution. J. Appl. Chem. USSR 1960, 33, 1798-1807.
10. Jaksic, M. M. The effect of pH on graphite wear in a chlorate cell process. J. Appl. Electrochem. 1973, 3, 219-225.
11. Janes, M. Graphite anodes in brine electrolysis. Trans. Electrochem. Soc. 1947, 92, 23-44.
12. Eberil, V. I.; Kupovich, F. V. Influence of the NaCl concentration on magnitude of the anode potential and wear of the graphite anodes in electrochemical preparation of chlorates. Sov. Electrochem. 1970, 6, 324-326.
13. Agapova, R. A.; Elina, L. M. Influence of electrolyte pH on the behavior of graphite anodes under the conditions of electrochemical production of sodium chlorate. J. Appl. Chem. USSR 1971, 44, 1320-1324.
14. Agapova, R. A.; Elina, L. M. Influence of sodium chloride concentration and electrolyte temperature on the stability of graphite anode under the conditions of electrolytic production of chlorate. J. Appl. Chem. USSR 1971, 44, 1536-1539.
15. Eberil, V. I.; Elina, L. M. Some peculiarities of the behavior of graphite anodes in the electrolysis of solutions of NaCl and, in particular, in the production of chlorates. Sov. Electrochem. 1970, 6, 758-762.
16. Shiyapnikov, V. A. Role of the anode material in electrosynthesis of chlorates. J. Appl. Chem. USSR 1976, 49, 86-89.
17. Udupa, H. V. K.; Sampath, S.; Narasimham, K. C.; Sundararajan, S.; Nagalingam, M.; Thiagarajan, N.; Govinda Rao, P.; Raju, C. J.; Chandran, T. J. V.; Kandasamy, S.; Subramanian, G.; Namboodri, P. N. N.; Natarajan, S. Use of graphite substrate lead dioxide anode in the preparation of chlorates. Ind. J. Technol. 1966, 4, 305-306.
18. Udupa, H. V. K.; Sampath, S.; Narasimham, K. C.; Nagalingam, M.; Thiagarajan, N.; Subramanian, G.; Natarajan, S.; Subbiah, P.; Palanisamy, R.; John Peter, S.; Pushpavanam, S.; Sadagopalan, M. Production of sodium chlorate using graphite substrate lead dioxide anodes: scaling up to 800 amp cells. Ind. J. Technol. 1971, 9, 257-261.
19. Ilin, K. G.; Skripchenko, V. I. Effect of the nature of the electrolyte cation on the anode process in the electrolysis of solutions of alkali and alkaline earth metal chlorides. Sov. Electrochem. 1961, 3, 261-266.
20. Pushpavanam, S.; Mohan, S.; Vasudevan, S.; Ravichandran, S.; Narasimham, K. C. Magnesium chlorate by electrolysis of magnesium chloride. Bull. Electrochem. 1990, 6, 422-423.
21. Vasudevan, S.; Pushpavanam, S.; Mohan, S.; Narasimham, K. C. Electrolytic preparation of strontium chlorate from strontium chloride. Proceedings of the Second National Conference on Electrochemical, held at HT, Bombay, India, 1990.
22. Vasudevan, S.; Mohan, S.; Pushpavanam, S.; Narasimham, K. C. Electrolytic preparation of magnesium perchlorate. J. Appl. Electrochem. 1992, 22, 877-882.
23. Vasudevan, S.; Pushpavanam, S.; Mohan, S.; Narasimham, K. C. Electrolytic Preparation of magnesium chlorate from magnesium chloride. J. Appl. Electrochem. 1992, 22, 1201-1204.
24. Pushpavanam, S.; Narasimham, K. C.; Vasu, K. I. Structural properties of Ru-Ti-Sn mixed oxide coatings. Bull Electrochem. 1988, 4, 979.
25. Vogel, A. I. Quantitative Inorganic Analysis; Libgnabs Green: London, 1964; pp 259-260.
26. Grant, J. Clowes and Coleman's Quantitative Analysis; Churchil: London, 1974; pp 176-178.
27. West, T. S.; Sykes, A. S. Analytical Applications of Diamino Ethane Tetra Acetic Acid; The British Drug House Ltd: England, 1960; p 59.
28. Vanmuylder, J.; Pourbaix, M. In Atlas of Electrochemical Equilibria in Aquous Solutions: Barium; Vanmuylder, J., Pourbaix, M., Eds.; Pergamon: New York, 1966; pp 139-153.
29. Kuhn, A. T.; Chan, C. Y. pH changes at near electrode surfaces. J. Appl. Electrochem. 1983, 13, 189-207.
30. Kudrayavstev, N. T.; Yarlykov, M. M.; Melnikova, M. M. Investigation of the pH of the catholyte layer in electrolytes during electrodeposition of nickel and iron. J. Appl. Chem. USSR 1965, 38, 554-561.
31. Vasudevan, S.; Mohan, S.; Pushpavanam, S.; Narasimham, K. C. Chlorates and perchlorates of strontium by electrolysis. Bull. Electrochem. 1993, 9, 693-695.
32. Vogt, H. Chlorate electrosynthesis current efficiency equations based on dimensionless groups. J. Appl. Electrochem. 1992, 22, 1185-1191.
33. Linke, W. F. Solubilities; American Chemical Society: Washington, D.C. 1964; Vol. 2, p 516.
34. Deligianni, H.; Romankiw, L. T. A rotating pH electrode for measurement of surface pH during electrolysis;"Study of NiFe electrodeposition. Extended Abstracts, The Electrochemical Society, Fall Meeting, Seattle, WA, 1990, 90-2, 498.