Pd(0)-catalyzed PMHS reductions of aromatic acid chlorides to aldehydes

Organic Letters

Volumn 8, Issue 9, 2006, Pages 1887-1888

  Lee, Kyoungsoo ^a   Maleczka Jr , Robert E ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; CHLORIDE; FLUORIDE; PALLADIUM; POLYMETHYLHYDROSILOXANE; SILOXANE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; OXIDATION REDUCTION REACTION; SYNTHESIS;

ALDEHYDES; CATALYSIS; CHLORIDES; FLUORIDES; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PALLADIUM; SILOXANES;

EID: 33646445022     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol060463v     Document Type: Article

References (20)

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16. We cannot rule out fluoride converting a RCO-Pd(II)-Cl species to RCO-Pd(II)-F.
17. 4, filtered, and concentrated. Purification of the resulting residue by silica gel chromatography afforded the aldehyde.
18. Maleczka, R. E., Jr.; Rahaim, R. J., Jr.; Teixeira, R. R. Tetrahedron Lett. 2002, 43, 7087-7090.
19. No benzaldehyde was detected by GC.
20. Reactions run under anhydrous conditions have met with mixed results. We will disclose the details of these experiments once they are suitably understood.