Analysis of monoethanolamine and its oxidative degradation products during CO2 absorption from flue gases: A comparative study of GC-MS, HPLC-RID, and CE-DAD analytical techniques and possible optimum combinations

Industrial and Engineering Chemistry Research

Volumn 45, Issue 8, 2006, Pages 2437-2451

  Supap, Teeradet ^a   Idem, Raphael ^b   Tontiwachwuthikul, Paitoon ^b   Saiwan, Chintana ^a  

^a CHULALONGKORN UNIVERSITY   (Thailand)

^b UNIVERSITY OF REGINA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; AMINES; DEGRADATION; ELECTROLYTES; ELECTROPHORESIS; FLUE GASES; GAS CHROMATOGRAPHY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; OXIDATION;

CE-DAD ANALYTICAL TECHNIQUES; GAS CHROMATOGRAPHY-MASS SPECTROMETRY (GC-MS); HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY-REFRACTIVE INDEX DETECTION (HPLC-RID); MEA OXIDATIVE DEGRADATION SYSTEMS;

GAS ABSORPTION;

ABSORPTION; AMINES; DEGRADATION; ELECTROLYTES; ELECTROPHORESIS; FLUE GASES; GAS ABSORPTION; GAS CHROMATOGRAPHY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; OXIDATION;

EID: 33646270424     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie050559d     Document Type: Conference Paper

References (31)

1. Kohl, A. L.; Reisenfeld, F. C. Gas Purification, 4th ed.; Gulf Publishing Co.: Houston, TX, 1997.
2. Hendricks, C. Carbon Dioxide Removal from Coal-Fired Power Plants; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1994.
3. Astarita, G.; Savage, D. W.; Bisio, A. Gas Treating with Chemical Solvents; John Wiley & Sons: New York, 1983.
4. 2 Emissions from Coal-Fired Power Plants. Heat Recovery Syst. CHP 1995, 15 (2), 231.
5. Blake, R. J. How Acid-Gas Treating Processes Compare. Oil Gas J. 1967, (January), 105.
6. Rooney, P. C.; Bacon, T.; Dupart, M. S. Part 2: Effect of Heat Stable Salts on MDEA Solution Corrosivity. Hydrocarbon Process. 1997, (April), 65.
7. Hofmeyer, B. G.; Scholten, H. G.; Lloyd, W. G. Contamination and Corrosion in Monoethanolamine Gas Treating Solutions; Internal Report No. 722; The Dow Chemical Company: Midland, MI, 1965.
8. Blanc, C.; Grall, M.; Demarais, G. The Part Played by Degradation Products in the Corrosion of Gas Sweetening Plants Using DEA and MDEA. In Proceedings of the 32nd Annual Laurance Reid Gas Conditioning Conference; Oklahoma University: Normal, OK, 1982.
9. Rooney, P. C.; Dupait, M. S. Corrosion in Alkanolamine Plants: Causes and Minimization. In Corrosion 2000: NACE International Annual Conference and Exposition; Orlando, FL, 2000; Paper 494.
10. 2. In Corrosion 2000: NACE International Annual Conference and Exposition; Orlando, FL, 2000; Paper 496.
11. Howard, M.; Sargent, A. Operating Experiences at Duke Energy Field Services Wilcox Plant with Oxygen Contamination and Amine Degradation. In Proceedings of the 51st Annual Laurance Reid Gas Conditioning Conference; Oklahoma University: Normal, OK, 2001.
12. Supap, T.; Idem, R.; Veawab, A.; Aroonwilas, A.; Tontiwach-wuthikul, P.; Chakma, A.; Kybett, B. D. Kinetics of the Oxidative Degradation of Aqueous Monoethanolamine in Flue Gas Treating Unit. Ind. Eng. Chem. Res. 2001, 40, 3445.
13. Chi, S.; Rochelle, G. T. Oxidative Degradation of Monoethanolamine. Ind. Eng. Chem. Res. 2002, 41, 4178.
14. 2 Capture Conditions. Ind. Eng. Chem. Res. 2004, 43, 6400.
15. Brydia, L. E.; Persinger, H. E. Quantitative Gas Chromatographic Determination of Ethanolamines as Trifluoroacetyl Derivatives. Anal. Chem. 1967, 39, 1318.
16. Piekos, R.; Kobylczyk, K.; Grzybowski, J. Quantitative Gas Chromatographie Determination of Ethanolamine as Trimethylsilyl Derivatives. Anal. Chem. 1975, 47, 1157.
17. Kennard, M. L.; Meisen, A. Gas Chromatographic Technique for Analyzing Partially Degraded Diethanolamine Solutions. J. Chromatogr. 1983, 267, 373.
18. Dawodu, O. F.; Meisen, A. Gas Chromatographic Analysis of Alkanolamine Solutions Tenax-GC Using Capillary and Packed Columns. J. Chromatogr. 1993, 629, 297.
19. Dawodu, O. F.; Meisen, A. Identification of Degradation Products Resulting from Carbonyl Sulphide-Induced Degradation of Diethanolamine. J. Chromatogr. 1991, 587, 237.
20. 2 Capture Facility. Energy Fuels 2003, 17, 1034.
21. Rooney, P. C.; Dupart, M. S.; Bacon, T. R. Oxygen's Role in Alkanolamine Degradation. Hydrocarbon Process. 1998, (July), 109.
22. Kadnar, R.; Rieder, J. Determination of Anion in Amine Solutions for Sour Gas Treatment. J. Chromatogr. A 1995, 706, 339.
23. Kadnar, R. Determination of Amines used in the Oil and Gas Industry (Upstream Section) by Ion Chromatography. J. Chromatogr. A 1999, 850, 289.
24. Kaminski, M.; Jastrzebski, D.; Przyjazny, A.; Kartanowicz, R. Determination of the Amount of Wash Amines and Ammonium Ion in Desulfurization Products of Process Gases and Results of Related Studies. J. Chromatogr. A 2002, 947, 217.
25. Pereira, E. A.; Tavares, M. F. M. Determination of Volatile Corrosion Inhibitors by Capillary Electrophoresis. J. Chromatogr. A 2004, 1051, 303.
26. Altria, K. D.; Frake, P.; Gill, I.; Hadgett, T.; Kelly, M. A.; Rudd, D. R. Validated Capillary Electrophoresis Method for the Assay of a Range of Basic Drugs. J. Pharm. Biomed. Anal. 1995, 13, 951.
27. Altria, K. D.; Bryant, S. M.; Hadgett, T. A. Validated Capillary Electrophoresis Method for the Analysis of a Range of Acidic Drugs and Excipients. J. Pharm. Biomed. Anal. 1997, 15, 1091.
28. Rooney, P. C.; Daniels, D. D. Oxygen Solubility in Various Alkanolamine/ Water Mixtures. Pet. Technol. Q. 1998, 3 (1), 97.
29. 2 Absorption from Flue Gases. Ind. Eng. Chem. Res. 2005, 44, 945.
30. Polderman, L. D.; Dillon, C. P.; Steele, A. B. Why MEA Solution Breaks Down in Gas Treating Service. Oil Gas J. 1956, 54, 180.
31. Talzi, V. P.; Ignashin, S. V. NMR Study of Decomposition of Monoethanolamine under Conditions of Industrial Gas Treatment. Russ. J. Appl. Chem. 2002, 75 (1), 80.