Oxidation inhibitors for copper and iron catalyzed degradation of monoethanolamine in CO 2 capture processes

Industrial and Engineering Chemistry Research

Volumn 45, Issue 8, 2006, Pages 2513-2521

  Goff, George S ^a   Rochelle, Gary T ^a  

^a The University of Texas at Austin   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATING AGENTS; HEAT STABLE SALTS; MONOETHANOLAMINE (MEA); OXIDATIVE DEGRADATION;

CATALYSIS; CHELATION; CONCENTRATION (PROCESS); COPPER; DEGRADATION; IRON; OXIDATION; REACTION KINETICS;

AMINES;

AMINES; CATALYSIS; CHELATION; CONCENTRATION (PROCESS); COPPER; DEGRADATION; IRON; OXIDATION; REACTION KINETICS;

EID: 33646230805     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0490031     Document Type: Conference Paper

References (45)

1. Polderman, L. D.; et al. Why Monoethanolamine Solution Breaks Down in Gas-Treating Service. Oil Gas J. 1955, 54 (2), 180-3.
2. 2 Capture from Flue Gas by Aqueous Absorption/Stripping, DE-AF26-99FT01029; U.S. Department of Energy-Federal Energy Technology Center: Pittsburgh, PA, 2001.
3. Hook, R. J. An Investigation of Some Sterically Hindered Amines as Potential Carbon Dioxide Scrubbing Compounds. Ind. Eng. Chem. Res. 1997, 36(5), 1779-1790.
4. Asperger, R. G.; Tebbal, S.; Kane, R. D. (CLI International, Inc.) Corrosion Inhibitor and Its Use; Patent Application WO 9828381 A1 19980702, 1998.
5. Mago, B. F.; et al. Corrosion Inhibitors for Alkanolamine Gas Treating System. U.S. Patent 3 959 170, 1976.
6. Pearce, R. L. Removal of Carbon Dioxide From Industrial Gases. U.S. Patent 4 440 731, 1984.
7. Pearce, R. L.; et al. Recovery of Carbon Dioxides from Gases. U.S. Patent 2 135 900, 1984.
8. Ranney, M. W. Corrosion Inhibitors-Manufacture and Technology; Noyes Data Corporation: Park Ridge, NJ, 1976.
9. Carbon Dioxide Absorbants. Contract No. 50023; Girdler Corporation, Gas Processes Division: Louisville, KY, June l, 1950.
10. Blachly, C. H.; et al. The Stabilization of Monoethanolamine Solutions for Submarine Carbon Dioxide Scrubbers; AD609888, NRL-FR-6189, NRL-6189; Naval Research Laboratory: Washington, DC, 1964.
11. Blachly, C. H.; et al. The Effect of Trace Amounts of Copper on the Stability of Monoethanolamine Scrubber Solutions; NRL-MR-1482; U.S. Naval Research Laboratory: Washington, DC, December 1963; p 9.
12. Chi, S.; et al. Oxidative Degradation of Monoethanolamine. Ind. Eng. Chem. Res. 2002, 41 (17), 4178-4186.
13. Hoftneyer, B. G.; et al. Contamination and Corrosion in Monoethanolamine Gas Treating Solutions. Am. Chem. Soc., Div. Petrol. Chem., Preprints 1956, 1 (2), 91-99.
14. 2 Capture Systems Under Absorber Conditions; Gale, J., et al., Eds.; 6th International Conference on Greenhouse Gas Control Technologies, Kyoto, Japan, 2003; Elsevier: Oxford, 2003; pp 115-120.
15. Hull, L. A.; et al. Oxidations of Amines. III. Duality of Mechanism in the Reaction of Amines with Chlorine Dioxide. J. Am. Chem. Soc. 1967, 89(5), 1163-1170.
16. Petryaev, E. P.; et al. Homolytic Deamination of Amino Alcohols. Zh. Org. Khim. 1984, 20 (1), 29-34.
17. Rooney, P. C.; et al. Oxygen's Role in Alkanolamine Degradation. Hydrocarbon Process. 1998, 77(7), 109-113.
18. 2 Mass Transfer. Ph.D. Thesis, The University of Texas at Austin, Austin, TX, 2005.
19. 2 Capture Conditions. Ind. Eng. Chem. Res. 2004, 43 (20), 6400-6408.
20. Tanthapanichakoon, W.; et al. Heat Stable Salts and Corrosivity in Amine Treating Units; Greenhouse Gas Control Technologies, Proceedings of the 6th International Conference on Greenhouse Gas Control Technologies: Kyoto, Japan, October 1-4, 2002; Pergamon: New York, 2003; Vol. 2, pp 1591-1594.
21. Chi, Q. S. Oxidative Degradation of Monoethanolamine. M.S. Thesis, The University of Texas at Austin, Austin, TX, 2000.
22. 2; GPA Research Report No. 152; Gas Processors Association: Tulsa, OK, 1996.
23. 2 in a 30 Mass Percent Monoethanolamine Solution. Can. J. Chem. Eng. 1995, 73 (1), 140-147.
24. Somogyi, L. P. Food Additives in Kirk-Othmer Encyclopedia of Chemical Technology; http://www.mrw.interscience.wiley.com/kirk/articles/ foodfrie.a01/frame.html (accessed October 2004).
25. White, J. C. Deaerator Providing Control of Physicochemical Oxygen Scavenging in Boiler Feedwaters; U.S. Patent Application 20010045396, 2001.
26. 2 from Waste Gas Streams Using Amines as Absorbents; U.S. Patent Application 2004253159, 2004.
27. Ulrich, R. K. Sulfite Oxidation Under Flue Gas Desulfurization Conditions: Enhanced Oxygen Absorption Catalyzed by Transition Metals. Ph.D. Thesis, The University of Texas at Austin, Austin, TX, 1983.
28. Lee, Y. J. Oxidative Degradation of Organic Acids Conjugated with Sulfite Oxidation in Flue Gas Desulfurization. Ph.D. Thesis, The University of Texas at Austin, Austin, TX, 1986.
29. Kohl, A.; et al. Gas Purification, 5th ed.; Gulf Publishing Co.: Houston, 1997.
30. 2 Recovery from Flue Gas/Turbine Exhaust Gas: Kerr-McGee/Lummus Carbon Dioxide Recovery Technology; ABB Lummus Global: Bloomfield, NJ, 1998; p 12.
31. Barron, C. H.; et al. Reaction Kinetics of Sodium Sulfite Oxidation by the Rapid Mixing Methodology. Chem. Eng. Sci. 1966, 21, 397-404.
32. Conklin, M. H.; et al. Metal Ion-Sulfur(IV) Chemistry. 2. Kinetic Studies of the Redox Chemistry of Copper(II)-Sulfur(IV) Complexes. Environ. Eng. Sci. 1988, 22 (8), 891-898.
33. Bengtsson, S.; et al. Catalytic Oxidation of Sulphite in Diluted Aqueous Solutions. Chem. Eng. Sci. 1975, 30, 1429-1435.
34. Chen, T.-I.; et al. Some Aspects of the Homogeneous Kinetics of Sulfite Oxidation. Ind. Eng. Chem. Fundam. 1972, 11 (4), 466-470.
35. 2 Capture from Flue Gas by Aqueous Absorption/Stripping. LRGCC Conf. Proceed. 2003, 53, 131-152.
36. Fessenden, R. J.; et al. Organic Chemistry, 5th ed.; Brooks/Cole Publishing Company: Pacific Grove, CA, 1994.
37. EPA Technology Transfer Network Air Toxics Website, The original list of hazardous air pollutants; http://www.epa.gov/ttn/atw/ orig189.html (accessed March 2005).
38. Veldman, R. R.; Trahan, D. Oxygen Scavenging Solutions for Reducing Corrosion by Heat Stable Amine Salts, U.S. Patent 5 686016, 1997.
39. Veldman, R. R.; Trahan, D. O. (Coastal Chemical Co., LLC) Addition of Oxygen Scavengers as Corrosion Inhibitors to Alkanolamine Solutions for Treatment of Natural Gas and Petroleum Fluids, U.S. Patent 6299836, 2001.
40. Wiberg, K. B.; et al. The Mechanism of Permanganate Oxidation. I. The Oxidation of Some Aromatic Aldehydes. J. Am. Chem. Soc. 1955, 77, 1786-1795.
41. Taylor, S. M.; et al. Kinetics of the Permanganate Oxidation of Formic Acid and Formate Ion in Aqueous Solution. J. Am. Chem. Soc. 1959, 81, 2933-2938.
42. Blachly, C. H.; et al. Stabilization of Monoethanolamine Solutions in Carbon Dioxide Scrubbers. J. Chem. Eng. Data 1966, 11 (3), 401-403.
43. Blachly, C. H.; et al. Studies of Submarine Carbon Dioxide Scrubber Operation: Effect of an Additive Package for the Stabilization of Monoethanolamine Solutions; NRL-MR-1598; U.S. Naval Research Laboratory: Washington, DC, March 1965.
44. Seibig, S.; et al. Kinetics of [FeII(EDTA)] Oxidation by Molecular Oxygen Revisited. New Evidence for a Multistep Mechanism. Inorg. Chem. 1997, 36(18), 4115-4120.
45. Cullinane, J. T. Thermodynamics and Kinetics of Aqueous Piperazine with Potassium Carbonate for Carbon Dioxide Absorption. Ph.D. Thesis, The University of Texas at Austin, Austin, TX, 2005.