Dispersion copolymerization of acrylamide with quaternary ammonium cationic monomer in aqueous salts solution

European Polymer Journal

Volumn 42, Issue 6, 2006, Pages 1284-1297

  Chen, Dongnian ^a,b   Liu, Xiaoguang ^a,b   Yue, Yumei ^a,b   Zhang, Wende ^a   Wang, Pixin ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Aqueous media; Cationic polyacrylamide; Dispersion polymerization; Particle formation mechanism

Indexed keywords

AMMONIUM COMPOUNDS; COPOLYMERIZATION; MOLECULAR WEIGHT; MORPHOLOGY; ORGANIC POLYMERS;

AQUEOUS MEDIA; CATIONIC POLYACRYLAMIDE; DISPERSION POLYMERIZATION; PARTICLE FORMATION MECHANISM;

ACRYLIC MONOMERS;

EID: 33646185200     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2005.12.007     Document Type: Article

References (32)

1. Kawaguchi S., and Ito K. Dispersion polymerization. Adv Polym Sci 175 (2005) 299-328
2. Barrett K.E.J. Dispersion polymerization in organic media (1975), Wiley, New York
3. Ober C.K., and Lok K.D. Formation of large monodisperse copolymer particles by dispersion polymerization. Macromolecules 20 (1987) 268-273
4. Paine A.J., Luymes W., and McNulty J. Dispersion polymerization of styrene in polar solvents. 6. Influence of reaction parameters on particle size and molecular weight in poly(N-vinylpyrrolidone)-stabilized reactions. Macromolecules 23 (1990) 3104-3109
5. Paine A.J. Dispersion polymerization of styrene in polar solvents. 7. A simple mechanistic model to predict particle size. Macromolecules 23 (1990) 3109-3117
6. Kawaguchi S., Winnik M.A., and Ito K. Dispersion copolymerization of n-butyl methacrylate with poly(ethylene oxide) macromonomers in methanol-water. Comparison of experiment with theory. Macromolecules 28 (1995) 1159-1166
7. Ho C., Chen S., Amiridis M.D., and Zee J.W.V. Dispersion polymerization of styrene in alcohol media: effect of initiator concentration, solvent polarity, and temperature on the rate of polymerization. J Polym Sci, Part A: Polym Chem 35 (1997) 2907-2915
8. Liu J., Chew C.H., Wong S.Y., Gan L.M., and Lin J. Dispersion polymerization of styrene in aqueous ethanol media using poly(ethylene oxide) macromonomer as a polymerizable stabilizer. Polymer 39 2 (1998) 283-289
9. Winzor C.L., Marzek Z., Winnik M.A., Croucher M.D., and Riess G. Stabilization of dispersion polymerization by poly(styrene-b-ethylene oxide) copolymers. Eur Polym J 30 1 (1994) 121-128
10. Shen S., Sudol E.D., and El-aasser M.S. Dispersion polymerization of methyl methacrylate: mechanism of particle formation. J Polym Sci, Part A: Polym Chem 32 (1994) 1087-1100
11. Baran N., Deniz S., Akgun M., Uzun I.M., and Dincer S. Dispersion polymerization of styrene in supercritical carbon dioxide using monofunctional perfluoropolyether and silicone-containing fluoroacrylate stabilizers. Eur Polym J 41 (2005) 1159-1167
12. Woods H.M., Nouvel C., Licence P., Irvine D., and Howdle S.M. Dispersion polymerization of methyl methacrylate in supercritical carbon dioxide: an investigation into stabilizer anchor group. Macromolecules 38 (2005) 3271-3283
13. Ray B., and Mandal B.M. Dispersion polymerization of acrylamide. Langmuir 13 (1997) 2191-2196
14. Mandal B.M., and Ray B. Dispersion polymerization of acrylamide: Part II. 2,2′-Azobisisobutyronitrile initiator. J Polym Sci, Part A: Polym Chem 37 (1999) 493-499
15. Guha S., and Mandal B.M. Dispersion polymerization of acrylamide: III. Partial isopropyl ester of poly(vinyl methyl ether-alt-maleic anhydride) as a stabilizer. J Colloid Interface Sci 271 1 (2004) 55-59
16. Ye Q., Zhang Z., Jia H., He W., and Ge X. Formation of monodisperse polyacrylamide particles by radiation-induced dispersion polymerization: particle size and size distribution. J Colloid Interface Sci 253 (2002) 279-284
17. Cho M.S., Yoon K.J., and Song B.K. Dispersion polymerization of acrylamide in aqueous solution of ammonium sulfate: synthesis and characterization. J Appl Polym Sci 83 (2002) 1397-1405
18. Song B.K., Cho M.S., Yoon K.J., and Lee D.C. Dispersion polymerization of acrylamide with quaternary ammonium cationic comonomer in aqueous solution. J Appl Polym Sci 87 (2003) 1101-1108
19. Ye Q., Zhang Z., and Ge X. Highly efficient flocculant synthesized through the dispersion copolymerization of water-soluble monomers induced by γ-ray irradiation: synthesis and polymerization kinetics. J Appl Polym Sci 89 (2003) 2108-2115
20. Tanaka H. Copolymerization of cationic monomers with acrylamide in an aqueous solution. J Polym Sci, Part A: Polym Chem Edit 24 (1986) 29-36
21. Okada T., Ishigaki I., Suwa T., and Machi S. Synthesis of cationic flocculant by radiation-induced copolymerization of methyl chloride salt of N,N-dimethylaminoethyl methacrylate with acrylamide in aqueous solution. J Appl Polym Sci 24 (1979) 1713-1721
22. Mabire F., Audebert R., and Quivoron C. Synthesis and solution properties of water soluble copolymers based on acrylamide and quaternary ammonium acrylic comonomer. Polymer 25 (1984) 1317-1322
23. Ge X., Ye Q., Xu X., Zhang Z., and Chu G. Studies of inverse emulsion copolymerization of (2-methacryloyloxyethyl) trimethyl ammonium chloride and acrylamide. J Appl Polym Sci 67 (1998) 1005-1010
24. Baade W., and Reichert K.H. Kinetics of the dispersion polymerization of acrylamide. Eur Polym J 20 (1984) 505-512
25. Becker LW, Larson EH. Inverse emulsion polymers with improved incorporation of diallyldimethyl ammoninum chloride. US Pat 4617362, 1986.
26. Cizravi J.C., Tay T.Y., and Pon E.C. Kinetics of azo-initiated 1-vinyl-2pyrrolidone polymerizations at low conversions in aqueous media. J Appl Polym Sci 75 (2000) 239-246
27. Chen D, Lin X, Yue Y, Zhang W, Wang P. Study of dispersion polymerization of acrylamide and cationic monomer in aqueous ammonium sulfate solution. Acta Polym Sin, in press.
28. Vu C., and Cabestany J. Characterization of cationic water-soluble polyacrylamide. J Appl Polym Sci 42 (1991) 2587-2869
29. Zhou Z., Gu X., and Ma J. Foundations of colloid chemistry (1987), Beijing University Press, Beijing
30. Paz Y., Kesselman E., Fahoum L., Portnaya I., and Ramon O. The interaction between poly(N-isopropylacrylamide) and salts in aqueous media: The "salting-out" phenomenon as studied by attenuated total reflection/fourier transform infrared spectroscopy. J Polym Sci Part B 42 (2003) 33-46
31. Katchalsky A., and Michaeli I. Polyelectrolyte gels in salt solution. J Polym Sci 15 (1955) 69-86
32. Winkler R.G. Structure of polyelectrolyte solutions: influence of salt and chain flexibility. Macromol symp 211 (2004) 55-70