Surface-mediated formation of PBDD/Fs from the high-temperature oxidation of 2-bromophenol on a CuO/silica surface

Chemosphere

Volumn 63, Issue 8, 2006, Pages 1291-1299

  Evans, Catherine S ^a   Dellinger, Barry ^a  

^a LOUISIANA STATE UNIVERSITY   (United States)

Author keywords

Brominated flame retardants; Combustion; Heterogeneous reactions; Reaction mechanisms

Indexed keywords

BENZENE; CATALYST ACTIVITY; CHLORINATION; COPPER OXIDES; OXIDATION; PHENOLS; PYROLYSIS; REACTION KINETICS; SILICA;

BROMINATED FLAME RETARDANTS; BROMINATED HYDROCARBONS; HETEROGENEOUS REACTIONS; POLYBROMINATED BENZENES;

SURFACE REACTIONS;

COPPER; PHENOL DERIVATIVE; POLYBROMINATED DIBENZODIOXIN; SILICON DIOXIDE;

BENZENE; CATALYST ACTIVITY; CHLORINATION; COPPER OXIDES; OXIDATION; PHENOLS; PYROLYSIS; REACTION KINETICS; SILICA; SURFACE REACTIONS;

CATALYSIS; CHLORINATED HYDROCARBON; OXIDATION; SILICA; THERMAL DECOMPOSITION;

ARTICLE; BROMINATION; CATALYSIS; CHEMICAL REACTION; CHLORINATION; COMBUSTION; HIGH TEMPERATURE; OXIDATION KINETICS; PYROLYSIS; REACTION ANALYSIS; SURFACE PROPERTY;

EID: 33646175379     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2005.09.054     Document Type: Article

References (28)

1. Altwicker E.R. Some laboratory experimental designs for obtaining dynamic property data about dioxins. Sci. Total Environ. 104 (1991) 47
2. Altwicker E.R., Schonberg J.S., Konduri N.V., and Milligan M.S. Polychlorinated dioxin/furan formation in incinerators. Hazard. Waste Hazard. Mater. 7 (1990) 73
3. Born J.G.P., Louw R., and Mulder P. Fly ash catalyzed oxidation and oxychlorination of phenol. Organohalogen Compd. 3 (1990) 31
4. Christoskova S., Stoyanova M., and Georgieva M. Low-temperature iron-modified cobalt oxide system: Part 2. Catalytic oxidation of phenol in aqueous phase. J. Appl. Catal. A 208 (2001) 243
5. Dumlar R., Thoma H., Lenoir D., and Hutzinger O. PBDF and PBDD from the combustion of bromine containing flame retarded polymers: a survey. Chemosphere 19 12 (1989) 2023
6. Evans C.S., and Dellinger B. Mechanisms of dioxin formation from the high-temperature pyrolysis of 2-bromophenol. Environ. Sci. Technol. 37 (2003) 5574
7. Evans C.S., and Dellinger B. Mechanisms of dioxin formation from the high-temperature oxidation of 2-chlorophenol. Environ. Sci. Technol. 39 (2005) 122
8. Evans C.S., and Dellinger B. Mechanisms of dioxin formation from the high-temperature oxidation of 2-bromophenol. Environ. Sci. Technol. 39 (2005) 2128
9. Evans C.S., and Dellinger B. Mechanisms of surface-mediated formation of PBDD/Fs from the high-temperature pyrolysis of 2-bromophenol on a CuO/silica surface. Environ. Sci. Technol. 39 13 (2005) 4857
10. Farquar G.R., Alderman S.L., Poliakoff E.D., and Dellinger B. X-ray spectroscopic studies of the high temperature reduction of Cu(II)O by 2-chlorophenol on a simulated fly ash surface. Environ. Sci. Technol. 37 (2003) 931
11. Huang H., and Buekens A. On the mechanisms of dioxin formation in combustion processes. Chemosphere 31 (1995) 4099
12. Kanters J., and Louw R. Thermal and catalysed halogenation in combustion reactions. Chemosphere 32 1 (1996) 87
13. Lanier W.S., Von Alten T.R., and Kilgroe J.D. Assessment of Trace Organic Emissions Test Results from the Montgomery Country South MWC in Dayton, Ohio (1990), Energy Environ. Anal. Inc., Durham, NC
14. Lemieux P.M., and Ryan J.V. Enhanced formation of dioxins and furans from combustion devices by addition of trace quantities of bromine. Waste Manage. 18 (1998) 361
15. Lomnicki S., and Dellinger B. A detailed mechanism of the surface-mediated formation of PCDD/F from the oxidation of 2-chlorophenol on a CuO/silica surface. J. Phys. Chem. A 107 (2003) 4387
16. Lomnicki, S., Dellinger, B., 2002. Formation of PCDD/F from the pyrolysis of 2-chlorophenol on the surface of dispersed copper oxide particles. In: Proceedings of the 29th Symposium on Combustion. vol. 29(2), p. 2463.
17. McMillen D.F., and Golden D.M. Hydrogen bond dissociation energies. Annu. Rev. Phys. Chem. 33 (1982) 493
18. McNaught A.D., and Wilkinson A. IUPAC Compendium of Chemical Terminology, vol. 68. second ed. (1997), Blackwell Science p. 171
19. Mennear J.H., and Lee C.C. Polybrominated dibenzo-p-dioxins and dibenzofurans: literature review and health assessment. Environ. Health Perspect. 102 1 (1994) 265
20. Öberg T., Warman K., and Bergstrom S. Brominated aromatics from combustion. Chemosphere 16 (1987) 2451
21. Rubey W.A., and Grant R.A. Design aspects of a modular instrumentation system for thermal diagnostic studies. Rev. Sci. Instrum. 59 (1988) 265
22. Sakai S. Thermal behavior of brominated flame retardants and PBDDs/DFs. Organohalogen Compd. 47 (2000) 210
23. Sidhu S.S., Maqsud L., and Dellinger B. The homogeneous, gas-phase formation of chlorinated and brominated dibenzo-p-dioxins from 2,4,6-trichlorophenol and 2,4,6-tribromophenols. Combust. Flame 100 (1995) 11
24. Söderstrom G., and Marklund S. PBCDD and PBCDF from incineration of waste-containing brominated flame retardants. Environ. Sci. Technol. 36 (2002) 1959
25. Stieglitz L., Vogg H., Zwick G., Beck J., and Bautzx H. On formation conditions of organohalogen compounds from particulate carbon of fly ash. Chemosphere 23 (1991) 1255
26. Thomas V.M., and Spiro T.G. The US dioxin inventory: Are there missing sources?. Environ. Sci. Technol. 30 (1996) 82A
27. US Environmental Protection Agency, 2001. Database of Sources of Environmental Release of Dioxin-like Compounds in the United States, EPA/600/C-01/012.
28. Weber L.W., and Greim H. The toxicology of brominated and mixed-halogenated dibenzo-p-dioxins and dibenzofurans: an overview. J. Toxicol. Environ. Health 50 3 (1997) 195