Solvent and ligand partition reaction pathways in nickel-mediated carboxylation of methylenecyclopropanes

Chemical Communications

Volumn 6, Issue 6, 2006, Pages 643-645

  Murakami, Masahiro ^a   Ishida, Naoki ^a   Miura, Tomoya ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBENE; CARBON DIOXIDE; CYCLOPROPANE DERIVATIVE; LIGAND; NICKEL COMPLEX; SOLVENT;

ARTICLE; CARBOXYLATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; LIGAND BINDING; REACTION ANALYSIS; STOICHIOMETRY; STRUCTURE ANALYSIS;

EID: 33646057698     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b515684j     Document Type: Article

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25. Product 4a can result from carboxylation of 1-phenylbuta-1,3-diene, to which 1a may possibly isomerise in the presence of nickel(0). The present reaction conditions, however, caused no carboxylation reaction of 1-phenylbuta-1,3-diene prepared independently
26. The contrasting results obtained with 1g and (arylmethylidene)cyclopropanes 1a-1f are accounted for by assuming the more stable nature of the nickel-benzylic carbon linkage of II