Chemical and structural variability of illitic phases formed from kaolinite in hydrothermal conditions

Applied Clay Science

Volumn 32, Issue 1-2, 2006, Pages 111-124

  Bentabol, María ^a   Ruiz Cruz, María Dolores ^a   Javier Huertas, Francisco ^b   Linares, José ^b  

^a UNIVERSITY OF MÁLAGA   (Spain)

^b CSIC   (Spain)

Author keywords

Hydrothermal synthesis; Illite; Kaolinite; Mixed layer minerals; TEM AEM; XRD; Zeolite

Indexed keywords

CRYSTALLIZATION; DISSOLUTION; HYDROTHERMAL SYNTHESIS; MAGNESIUM PRINTING PLATES; PH EFFECTS; PHASE TRANSITIONS; PRECIPITATION (CHEMICAL); TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION ANALYSIS; ZEOLITES;

ILLITE; KAOLINITE; MIXED-LAYER MINERALS;

KAOLIN;

CHEMICAL COMPOSITION; ILLITE; KAOLINITE; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION; ZEOLITE;

EID: 33645900583     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2005.12.003     Document Type: Article

References (34)

1. Altaner S.P., and Grim R.E. Mineralogy, chemistry, and diagenesis of tuffs in the Sucher Creek Formation (Miocene), eastern Oregon. Clays Clay Miner. 38 (1990) 561-572
2. Bauer A., Velde B., and Berger G. Kaolinite transformation in high molar KOH solutions. Appl. Geochem. 5 (1998) 619-629
3. Bentabol, M. 2003. Transformaciones hidrotermales de la caolinita. Ph.D. Thesis. Universidad de Málaga. 395 pp.
4. Bentabol M., Ruiz Cruz M.D., Huertas F.J., and Linares J. Hydrothermal transformation of kaolinite to illite at 200 °C. Clay Miner. 38 (2003) 161-172
5. Bowers T.S., and Burns R.G. Activity diagrams for clinoptilolite: susceptibility of the zeolite to further diagenetic reactions. Am. Mineral. 75 (1990) 601-619
6. 4+ content of natural phengites: a discussion. Contrib. Mineral. Petrol. 17 (1968) 78-81
7. Chermak J.A., and Rimstidt J.D. The hydrothermal transformation rate of kaolinite to muscovite/illite. Geochim. Cosmochim. Acta 54 (1990) 2979-2990
8. Deer W.A., Howie R.A., and Zussman J. Rock-forming minerals. Sheet Silicates vol. 3 (1972), Longman, London 270 pp.
9. Fiore S., Huertas F.J., Huertas F., and Linares J. Smectite formation from rhyolitic obsidian as inferred by microscopic (SEM-TEM-AEM) investigation. Clay Miner. 36 (2001) 489-500
10. Frey M. A mixed-layer paragonite/phengite of low-grade metamorphic origin. Contrib. Mineral. Petrol. 24 (1969) 63-65
11. Frey M. The steps from diagenesis to metamorphism in pelitic rocks during Alpine orogenesis. Sedimentology 15 (1970) 261-279
12. Frey M. Very low-grade metamorphism of clastic sedimentary rocks. In: Frey M. (Ed). Low Temperature Metamorphism (1987), Blackie and Son Ltd, Glasgow 9-58
13. Giese R.F. Kaolin minerals: structures and stabilities. In: Bailey S.W. (Ed). Hydrous phyllosilicates (exclusive of micas) Rev. Mineral. Min. Soc. Am. vol. 19 (1991) 29-66
14. González Jesús J., Huertas F.J., Linares J., and Ruiz Cruz M.D. Textural and structural transformations of kaolinite in aqueous solutions. Appl. Clay Sci. 17 (2000) 245-263
15. Guidotti C.V. Micas in metamorphic rocks. In: Bailey S.W. (Ed). Micas. Rev. In Mineral. Min. Soc. Am. vol. 13 (1987) 357-467
16. 2+ on the hydrothermal illitization reaction. Clays Clay Miner. 39 (1991) 387-399
17. Hower J., and Mowatt T.C. The mineralogy of illites and mixed-layers illite/montmorillonite. Am. Mineral. 51 (1966) 825-854
18. Huang W.-L. The formation of illitic clays from kaolinite in KOH solution from 225 °C to 350 °C. Clays Clay Miner. 41 (1993) 645-654
19. 3+ for Al substitution. Clays Clay Miner. 53 (2005) 1-10
20. Jiang W.-T., and Peacor D.R. Formation and modification of metastable sodium potassium mica, paragonite and muscovite in hydrothermally altered metabasites from northern Wales. Am. Mineral. 78 (1993) 782-793
21. Johnson J.W., Oelkers E.H., and Helgeson H.C. SUPCRT92: a software package for calculating the standard molal thermodynamic properties of mineral, gases, aqueous species and reactions from 1 to 5000 bar and 0 to 1000 °C. Comput. Geosci. 18 (1992) 899-947
22. Kharaka Y.K., Gunter W.D., Aggarwal P.K., Perkin E.H., and De Braal J.D. SOLMINEQ.88: a computer program for geochemical modelling of water-rock interaction. U.S. Geological Survey Water-Resources Investigation Report 88-4227. Washington (1988) 420 pp.
23. Kisch H.J. Mineralogy and petrology of burial diagenesis (burial metamorphism) and incipient metamorphism in clastic rocks. In: Larsen G., and Chilinger G.V. (Eds). Diagenesis in Sediments and Sedimentary Rocks (1983), Elsevier, Amsterdam 289-493
24. Li G., Peacor D.R., Merriman R.J., and Roberts B. The diagenetic to low-grade metamorphic evolution of matrix white micas in the system muscovite-paragonite in a mudrock from central Wales, United Kingdom. Clays Clay Miner. 42 (1994) 369-381
25. Livi K.J.T., Veblen D.R., Ferry J.M., and Frey M. Evolution of 2 : 1 layered silicates in low-grade metamorphosed Liassic shales of Central Switzerland. J. Metamorph. Geol. 15 (1997) 323-344
26. Lorimer G.W., and Cliff G. Analytical electron microscopy of minerals. In: Wenk H.R. (Ed). Electron Microscopy in Mineralogy (1976), Springer-Verlag, New York 506-519
27. Merriman R.J., and Roberts B. A survey of white mica crystallinity and polytypes in pelitic rocks of Snowdonia and Llyn, North Wales. Mineral. Mag. 49 (1985) 305-319
28. Newman A.C.D., and Brown G. The chemical constitution of clays. In: Newman A.C.D. (Ed). Chemistry of Clays and Clay Minerals (1987), Mineralogical Society, London 1-128
29. Reynolds R.C. Interstratified clay minerals. In: Brindley G.W., and Brown G. (Eds). Crystal Structures of Clay Minerals and their X-ray identification (1980), Mineralogical Society, London 249-303
30. Velde B. Experimental determination of muscovite polytypes stabilities. Am. Mineral. 50 (1965) 436-449
31. Weaver C.E., and Pollard L.D. The Chemistry of Clay Minerals (1973), Elsevier 213 pp.
32. Wolery T.J. EQ3/6, a Software Package for Geochemical Modelling of Aqueous Systems. (Version 7) (1992), Laurence Livermore National Laboratory, CA UCRL-MA-110662
33. V,sol. Geochim. Cosmochim. Acta 60 (1996) 1873-1883
34. V,sol. Geochim. Cosmochim. Acta 61 (1997) 3135-3144