Adsorption kinetics of Cu(II) ions using N,O-carboxymethyl-chitosan

Journal of Hazardous Materials

Volumn 131, Issue 1-3, 2006, Pages 103-111

  Sun, Shengling ^a,b   Wang, Aiqin ^a  

^a LANZHOU INSTITUTE OF CHEMICAL PHYSICS   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Adsorption; Carboxymethyl chitosan; Copper ions; Kinetics; Synthesis

Indexed keywords

ADSORPTION; ADSORPTION ISOTHERMS; COMPLEXATION; CORRELATION METHODS; REACTION KINETICS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); X RAY PHOTOELECTRON SPECTROSCOPY;

CARBOXYMETHYL-CHITOSAN; COPPER IONS; DEGREE OF SUBSTITUTION (DS); KINETICS;

COPPER;

ADSORBENT; CHELATE; CHITOSAN DERIVATIVE; CHLOROACETIC ACID; COPPER; POLYMER;

ADSORPTION; ADSORPTION ISOTHERMS; COMPLEXATION; COPPER; CORRELATION METHODS; REACTION KINETICS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); X RAY PHOTOELECTRON SPECTROSCOPY;

ADSORPTION; CHELATE; COPPER; FTIR SPECTROSCOPY; KINETICS; X-RAY SPECTROSCOPY;

ADSORPTION KINETICS; ARTICLE; COMPLEX FORMATION; CORRELATION ANALYSIS; INFRARED SPECTROSCOPY; ISOTHERM; MOLECULAR MODEL; PH MEASUREMENT; SUBSTITUTION REACTION; X RAY PHOTOELECTRON SPECTROSCOPY;

ACETIC ACIDS; ADSORPTION; CHITOSAN; COPPER; HYDROGEN-ION CONCENTRATION; KINETICS; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; TEMPERATURE;

EID: 33645876771     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2005.09.012     Document Type: Article

References (29)

1. Wan Ngah W.S., Endud C.S., and Mayanar R. Removal of copper(II) ions from aqueous solution onto chitosan and cross-linked chitosan beads. React. Funct. Polym. 50 (2002) 181-190
2. Juang R.S., and Shao H.J. A simplified equilibrium model for sorption of heavy metal ions from aqueous solutions on chitosan. Water Res. 36 12 (2002) 2999-3008
3. Huang C.P., Chung Y.C., and Liou M.R. Adsorption of Cu(II) and Ni(II) by pelletized biopolymer. J. Hazard. Mater. 45 (1996) 265-277
4. Wu F.C., Tseng R.L., and Juang R.S. Comparative adsorption of metal and dye on flake- and bead-types of chitosans prepared from fishery wastes. J. Hazard. Mater. B 73 (2000) 63-75
5. Chu K.H. Removal of copper from aqueous solution by chitosan in prawn shell: adsorption equilibrium and kinetics. J. Hazard. Mater. B90 (2002) 77-95
6. Evans J.R., Davids W.G., MacRae J.D., and Amirbahman A. Kinetics of cadmium uptake by chitosan-based crab shells. Water Res. 36 13 (2002) 3219-3226
7. Guibal E. Interactions of metal ions with chitosan-based sorbents: a review. Sep. Purif. Technol. 38 (2004) 43-74
8. Lee S.T., Mi F.L., Shen Y.J., and Shyu S.S. Equilibrium and kinetic studies of copper (II) ion uptake by chitosan-tripolyphosphate chelating resin. Polymer 42 (2001) 1879-1892
9. Rodrigues C.A., Laranjeira M.C., Favere V.T., and Stadler E. Interaction of Cu(II) on N-(2-pyridylmethyl) and N-(4-pyridylmethyl) chitosan. Polymer 39 (1998) 5121-5126
10. Inoue K., Yoshizuka K., and Ohto K. Adsorptive separation of some metal ions by complexing agent types of chemically modified chitosan. Anal. Chim. Acta 388 (1999) 209-218
11. Jia Z., Shen D., and Xu W. Synthesis and antibacterial activities of quaternary ammonium salt of chitosan. Carbohydr. Res. 333 (2001) 1-6
12. Zhao Z.P., Wang Z., Ye N., and Wang S.C. A novel N,O-carboxymethyl amphoteric chitosan/poly (ethersulfone) composite MF membrane and its charged characteristics. Desalination 144 (2002) 35-39
13. Liu X.F., Guan Y.L., Yang D.Z., Li Z., and Yao K.D. Antibacterial action of chitosan and carboxymethylated chitosan. J. Appl. Polym. Sci. 79 (2001) 1324-1335
14. Hon N.S., and Tang L.G. Chelation of chitosan derivatives with zinc ions. I. O,N-carboxymethyl chitosan. J. Appl. Polym. Sci. 77 (2000) 2246-2253
15. Muzzarelli R.A.A., and Petrarulo P.I. Solubility and structure of N-carboxymethyl chitosan. Int. J. Biol. Macromol. 16 (1994) 177-180
16. Zhang L., Guo J., Zhou J., Yang G., and Du Y.M. Blend membranes from carboxymethylated chitosan/alginate in aqueous solution. J. Appl. Polym. Sci. 77 (2000) 610-616
17. Nuhoglu Y., and Oguz E. Removal of copper(II) from aqueous solutions by biosorption on the cone biomass of Thuja orientalis. Process. Biochem. 38 (2003) 1627-1631
18. Chen X.G., and Park H.J. Chemical characteristics of O-carboxymethyl chitosans related to the preparation conditions. Carbohydr. Polym. 53 (2003) 355-359
19. Liu C.X., Chen G.H., Jin Z.T., Sun M.K., and Gao C.J. Modification of the formula for calculation of substitution degree of N,O-carboxymethyl chitosan. J. Beijing Univ. Chem. Technol. 31 (2004) 14-17 (in Chinese)
20. Lu S.J., Song X., and Cao D. Preparation of water-soluble chitosan. J. Appl. Polym. Sci. 91 (2004) 3497-3503
21. Justi K.C., Laranjeira M.C.M., and Neves A. Chitosan functionalized with 2-bis-(pyridylmethyl) aminomethyl-4-methyl-6-formyl-phenol: equilibrium and kinetics of copper(II) adsorption. Polymer 45 (2004) 6285-6290
22. 4 magnetic nanoparticles for removal of Cu(II) ions. J. Colloids Interf. Sci. 283 (2005) 446-451
23. Beppu M.M., Arruda E.J., Vieira R.S., and Santos N.N. Adsorption of Cu(II) on porous chitosan membranes functionalized with histidine. J. Membr. Sci. 240 (2004) 227-235
24. Mitani T., Kawakami T., Morishita M., Adachi Y., and Ishii H. Effect of copper adsorption on the mechanical properties of chitosan beads. J. Appl. Polym. Sci. 88 (2003) 2988-2991
25. Chiou M.S., and Li H.Y. Adsorption behaviour of reactive dye in aqueous solution on chemical cross-linked chitosan beads. Chemosphere 50 (2003) 1095-1105
26. Ngah W.S.W., Ab Ghani S., and Kamari A. Adsorption behaviour of Fe(II) and Fe(III) ions in aqueous solution on chitosan and cross-linked chitosan beads. Bioresour. Technol. 96 (2005) 443-450
27. Wu F.C., Tseng R.L., and Juang R.S. Kinetic modeling of liquid-phase adsorption of reactive dyes and metal ions on chitosan. Water Res. 35 3 (2001) 613-618
28. Lin Y.W., Chen W., Luo H.B., and Jiang Z. Study on the adsorption of Zn(II) in solution by carboxymethyl chitosan. Strait Pharmaceut. J. 12 3 (2000) 69-72 (in Chinese)
29. Wang X.H., Du Y.M., and Liu H. Preparation, characterization and antimicrobial activity of chitosan-Zn complex. Carbohydr. Polym. 56 (2004) 21-26