Reactivity of molybdenum and rhenium hydroxo complexes toward organic electrophiles: Reactions that afford carboxylato products

Organometallics

Volumn 25, Issue 7, 2006, Pages 1717-1722

  Guesta, Luciano ^a   Hevia, Eva ^a   Morales, Dolores ^a   Pérez, Julio ^a   Riera, Lucia ^a   Miguel, Daniel ^b  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOXYLATION; CARBOXYLIC ACIDS; CHEMICAL BONDS; ORGANOMETALLICS; REACTION KINETICS; X RAY DIFFRACTION;

CARBOXYLATO LIGANDS; PHENYL(ETHYL)KETENE; RHENIUM HYDROXO COMPLEXES; TRIFLATO COMPLEXES;

COMPLEXATION;

EID: 33645835675     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om051081g     Document Type: Article

References (43)

1. (a) Bryndza, H.; Tam, W. Chem. Rev. 1988, 88, 1163.
2. (b) Gilje, J. W.; Roesky, H. W. Chem. Rev. 1994, 94, 895.
3. (c) Fulton, J. R.; Holland, A. W.; Fox, D. J.; Bergman, R. G. Acc. Chem. Res. 2002, 55, 44.
4. Morales, D.; Clemente, M. E. N.; Pérez, J.; Riera, L.; Riera, V.; Miguel, D. Organometallics 2002, 21, 4934.
5. (a) Gibson, D. H.; Yin, X. J. Am. Chem. Soc. 1998, 120, 11200.
6. (b) Gibson, D. H.; Yin, X.; Hen, H.; Mashuta, M. S. Organometallics 2003, 22, 337.
7. (c) Cuesta, L.; Gerbino, D. C.; Hevia, E.; Morales, D.; Clemente, M. E. N.; Pérez, J.; Riera, L.; Riera, V.; Miguel, D.; del Río, I.; García-Granda, S. Chem. Eur. J. 2004, 10, 1775.
8. Gerbino, D. C.; Hevia, E.; Morales, D.; Clemente, M. E. N.; Pérez, J.; Riera, L.; Riera, V.; Miguel, D. Chem. Commun. 2003, 328.
9. Mandai, S. K.; Ho, D. M.; Orchin, M. Organometallics 1993, 12, 1714.
10. Darensbourg, Lee, W.-Z.; Phelps, A. L.; Guidry, E. Organometallics 2003, 22, 5585.
11. Simpson, R. D.; Bergman, R. G. Angew. Chem., Int. Ed. Engl. 1992, 37, 220.
12. Full X-ray data are given in the Supporting Information as CIF.
13. Modec, B.; Brencic, J. V. Inorg. Chem. Commun. 2004, 7, 516, and references therein.
14. Woerpel, K. A.; Bergman, R. G. J. Am. Chem. Soc. 1993, 115, 7888.
15. (a) Glueck, D. S.; Winslow, L. J. N.; Bergman, R. G. Organometallics 1991, 10, 1462.
16. (b) Simpson, R. D.; Bergman, R. G. Organometallics 1992, 11, 4306.
17. (c) Boncella, J. M.; Villanueva, L. R. J. Organomet. Chem. 1994, 465, 297.
18. Coue, L.; Cuesta, L.; Morales, D.; Halfen, J. A.; Pérez, J.; Riera, L.; Riera, V.; Miguel, D.; Connelly, N. G.; Boonyuen, S. Chem. Eur. J. 2004, 10, 1906.
19. Hevia, E.; Pérez, J.; Riera, L.; Riera, V.; del Río, I.; García-Granda, S.; Miguel, D. Chem. Eur. J. 2002, 8, 4510.
20. Zhang, C.; Liu, R.; Zhou, X.; Chen, Z.; Weng, L.; Lin, Y. Organometallics 2004, 23, 3246.
21. 2 some signals appear overlapped.
22. Hevia, E.; Pérez, J.; Riera, V.; Miguel, D. Organometallics 2003, 22, 257.
23. Hevia, E.; Pérez, J.; Riera, V.; Miguel, D.; Campomanes, P.; Menéndez, M. I.; Sordo, T. L.; García-Granda, S. J. Am. Chem. Soc. 2003, 125, 3706.
24. For recent overviews of ketene chemistry, see: (a) Tidwell, T. T. Angew. Chem., Int. Ed. 2005, 44, 5778 and 6812.
25. (a) Aida, T.; Inoue, S. Acc. Chem. Res. 1996, 29, 39.
26. (b) O'Keefe, B. J.; Hillmyer, M. A.; Tolman, W. B. Dalton Trans. 2001, 2215.
27. (c) Coates, G. W. Dalton Trans. 2002, 467.
28. (d) Bourissou, D.; Martin-Vaca, B.; Dumitrescu, A.; Graullier, M.; Lacoṁbe, F. Macromolecules 2005, 38, 9993.
29. (e) Bonnet, F.; Cowley, A. R.; Mountford, P. Inorg. Chem. 2005, 44, 9046.
30. (f) Barnea, E.; Moradove, D.; Berthet, J.-C.; Ephritikhine, M.; Eisen, M. S. Organometallics 2006, 25, 320.
31. Baigne, L. M.; Seiklay, H. R.; Tidwell, T. T. J. Am. Chem. Soc. 1985, 107, 5391.
32. Taylor, E. C.; McKillop, A.; Hawks, G. H. Org. Synth. 1980, 6, 549.
33. SAINT+, SAX area detector integration program, Version 6.02; Bruker AXS, Inc.: Madison, WI, 1999.
34. Sheldrick, G. M. SADABS, Empirical Absorption Correction Program; University of Göttingen: Göttingen, Germany, 1997.
35. Collect; Nonius BV: Amsterdam, 1997-2004.
36. Otwinowski, Z.; Minor, W. Methods Enzymol. 1997, 276, 307.
37. Blessing, R. H. Acta Crystallogr. 1995, A51, 33.
38. Sheldrick, G. M. SHELXTL, An integrated system for solving, refining, and displaying crystal structures from diffraction data, Version 5.1; Bruker AXS, Inc.: Madison, WI, 1998.
39. (a) Nardelli, M Comput. Chem. 1983, 7, 95.
40. (b) Nardelli, M. J. Appl. Crystallogr. 1995, 28, 659.
41. Flack, H. D. Acta Crystallogr. 1983, A39, 876.
42. Espartero, J. L.; Rashkov, I.; Li, S. M.; Manolova, N.; Vert, M. Macromolecules 1996, 29, 3535.
43. Frimer, A. A.; Gilinsky-Sharon, P. J. Org. Chem. 1995, 60, 2796.