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note
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Nucleophilic subtitution on carbon resulted in inversion of configuration in the case of compounds 8 (11) and 9 (12).
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In 2,2′-biphosphole, the inversion barrier for the pyramidal phosphorus is reduced, relative to that in phosphines, as a result of the increase in aromatic character of the phosphorus in the transition state; see ref 7.
-
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28
-
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33645818304
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-
note
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The driving force of this isomerization process should be the phosphorus inversion. No interconversion between a, b, and c occurred even at +90 °C in toluene according to NMR studies. In 2,2-biphosphole disulfides the pyramidal inversion at phosphorus is suppressed, as the lone pairs are masked by sulfur.
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29
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33645830642
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PP3.25; δp 52.9(8),δp 50.9(s)).
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