메뉴 건너뛰기




Volumn , Issue 7, 2006, Pages 1353-1361

Coordination dependence of magnetic properties within a family of related [FeII2] complexes of a triazine-based ligand

Author keywords

1,3,5 Triazine; Iron(II) complexes; Magnetic properties; Polydentate ligands; Spin crossover

Indexed keywords

GROUND STATE; HAMILTONIANS; IONS; IRON COMPOUNDS; LIGANDS; SINGLE CRYSTALS; TEMPERATURE;

EID: 33645782204     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200501022     Document Type: Article
Times cited : (35)

References (40)
  • 1
    • 42249095372 scopus 로고    scopus 로고
    • J. S. Miller, M. Drillon (Eds.), Wiley-VCH, Weinheim
    • J. S. Miller, M. Drillon (Eds.), Magnetism: Molecules to Materials V, Wiley-VCH, Weinheim, 2005.
    • (2005) Magnetism: Molecules to Materials V
  • 17
    • 85163225899 scopus 로고    scopus 로고
    • note
    • Complex 1 (77 K) presents an HS doublet with I.S. = 1.46, Q.S. = 3.45 and relative intensity = 37%, and an LS singlet with I.S. = 0.77, Q.S. = 0.26 and relative intensity = 63%.
  • 19
    • 85163228450 scopus 로고    scopus 로고
    • note
    • Note that a normalisation of the data has been performed to take into account the residual fraction of 37% at 77 K, as measured by Mössbauer spectroscopy. Such a high residual fraction, although often ascribed to defaults, may arise from a thermal equilibrium between states of the same energy (ΔH = 0) but with different degeneracies and thus degrees of freedom.
  • 27
    • 85163223743 scopus 로고    scopus 로고
    • note
    • i is the calculated value.
  • 31
    • 85163233353 scopus 로고    scopus 로고
    • note
    • 2 is not observed clearly in 1, probably because of overlap with metal to ligand charge transfer.
  • 37
    • 0008737909 scopus 로고    scopus 로고
    • Bruker Analytical X-ray Systems, version 6.0
    • SAINT, Software Users Guide, Bruker Analytical X-ray Systems, version 6.0, 1999.
    • (1999) SAINT, Software Users Guide


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.