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Volumn 110, Issue 9, 2006, Pages 3138-3150

Spin-lattice relaxation and rotational motion of aromatic triplet-state molecules in supercooled alkane solvents (part 1)

Author keywords

[No Author keywords available]

Indexed keywords

AMORPHOUS GLASSES; SOLVENT VISCOSITIES; SPIN-LATTICE RELAXATION; TRIPLET-STATE MOLECULES;

EID: 33645689667     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0545546     Document Type: Article
Times cited : (2)

References (61)
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    • to be submitted for publication (part 2)
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    • Ruth, A.A.1    Nickel, B.2
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    • We assume triplet-triplet annihilation and quenching processes to be negligible
    • We assume triplet-triplet annihilation and quenching processes to be negligible.
  • 16
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    • note
    • 1i (i = x, y, z), is referred to as OSP.
  • 21
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    • Polarized light in spectroscopy and photochemistry
    • Lamola, A. A., Ed.; Dekker: NewYork
    • Dörr, F. Polarized Light in Spectroscopy and Photochemistry. In Creation and Detection of the Excited State; Lamola, A. A., Ed.; Dekker: NewYork, 1971; Vol. 1, part A, p 53.
    • (1971) Creation and Detection of the Excited State , vol.1 , Issue.PART A , pp. 53
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    • note
    • The cuvette can be moved horizontally and vertically as well as rotated about a vertical axis in steps of 90°. Therefore, photochemical degradation of the sample is roughly 100 times slower than it is with an immobile sample.
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    • Dissertation, University of Göttingen, Göttingen, Germany
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    • (1992)
    • Ruth, A.A.1
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    • note
    • -1, with n = 1, ..., 4.
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    • Hovi, V., Ed.; North-Holland Publishing: Amsterdam
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    • (1973) 17. Congress Ampère, Proc. Col. Ampère , vol.17 , pp. 143
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    • 15 cP)
    • 15 cP).
  • 40
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    • For stick boundary conditions to hold, the tangential velocities of the solute and the solvent molecules at the solute-solvent interface are assumed to be the same
    • For stick boundary conditions to hold, the tangential velocities of the solute and the solvent molecules at the solute-solvent interface are assumed to be the same.
  • 41
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    • One of the transition moments involved (either that for emission or that for absorption) must be polarized along the rotational axis of the ellipsoid for eq 11 to hold
    • One of the transition moments involved (either that for emission or that for absorption) must be polarized along the rotational axis of the ellipsoid for eq 11 to hold.
  • 47
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    • If no tangential force is exerted on the rotating molecule by the solvent, the boundary condition is known to be"slip". Spheres experience zero friction for slip conditions
    • If no tangential force is exerted on the rotating molecule by the solvent, the boundary condition is known to be"slip". Spheres experience zero friction for slip conditions.
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    • Linear response theory and spin-relaxation
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    • note
    • 2
  • 61
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    • In ref 2 the three components were referred to as α-OR, β-OR, and γ-OR
    • In ref 2 the three components were referred to as α-OR, β-OR, and γ-OR.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.