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33645500613
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note
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The monomer conversion was calculated from the ratio of monomer to solvent (DMAc), whereby the solvent was applied as internal standard.
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14
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33645511856
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note
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AB).
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17
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0001088924
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33645514449
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note
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2 ≈ 1, the reactivity of monomers A and B to itself and to the other monomer are equal, resulting in a statistical distribution of the monomers throughout the polymer chains.
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21
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33645525776
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note
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2 < 1, the reactivity of monomer A to itself is larger than to monomer B, and the reactivity of monomer B to itself is lower than to monomer A.; therefore, monomer A will be incorporated faster in the beginning of the polymerization, and during the polymerization more and more of monomer B will be incorporated due to its increasing concentration, as compared to the concentration of monomer A. As a result, the polymer chains will have a gradient in the monomer composition.
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24
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3943084131
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10644248285
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Wijnans, S.1
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