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33645467397
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note
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Nonhexagonal TMA structures have been created on Au surfaces by potential-induced adsorption (ref 9) and on the anisotropic (110) surface of Cu by coordination to metals (ref 11).
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0001170113
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Two-fold packing of molecules with three-fold symmetry on a substrate with three-fold symmetry (HOPG) has been reported for conformationally mobile derivatives of triphenylene and hexabenzocoronene. However, such self-assembly does not have pronounced directionality: (a) Askadskaya, L.; Boeffel, C.; Rabe, J. P. Ber. Bunsen-Ges. Phys. Chem. 1993, 97, 517.
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Askadskaya, L.1
Boeffel, C.2
Rabe, J.P.3
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20
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33748216871
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(b) Stabel, A.; Herwig, P.; Müllen, K.; Rabe, J. P. Angew. Chem., Int. Ed. 1995, 34, 1609.
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Rabe, J.P.4
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21
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33645465380
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note
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However, the esterification is not expected to occur within minutes at 20 °C with no catalyst. Furthermore. NMR and mass spectrometry analyses of mixtures of undecanol, TMA, and heptanoic acid incubated at 100 °C for 1 h over HOPG showed no sign of the ester.
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23
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33645468840
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note
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The distance between TMA molecules in the X-ray structure (0.96 nm) fits well the separation between the bright spots along the TMA tape (W = 0.97 ± 0.06 nm, Figure 1c).
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24
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0001750895
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(a) Hibino, M.; Sumi, A.; Tsuchiya, H.; Hatta, I. J. Phys. Chem. B 1998, 102, 4544.
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0037426873
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