Positive homotropic allosteric binding of silver(I) cations in a Schiff base oligopyrrolic macrocycle

Journal of the American Chemical Society

Volumn 128, Issue 13, 2006, Pages 4184-4185

  Sessler, Jonathan L ^a   Tomat, Elisa ^a   Lynch, Vincent M ^a  

^a UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATION; COORDINATION COMPOUND; MACROCYCLIC COMPOUND; OLIGOMER; PYRROLE DERIVATIVE; SCHIFF BASE; SILVER;

ALLOSTERISM; ARTICLE; BINDING AFFINITY; BINDING SITE; CHEMICAL BINDING; COMPLEX FORMATION; CONFORMATION; HYDROGEN BOND; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE; STEREOCHEMISTRY; SYNTHESIS; X RAY DIFFRACTION;

CATIONS, MONOVALENT; HYDROGEN BONDING; KINETICS; MACROCYCLIC COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; PYRROLES; SCHIFF BASES; SILVER; X-RAY DIFFRACTION;

EID: 33645469329     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0582004     Document Type: Article

References (12)

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12. The hydrogen-bonding acetate ions shown in Figure 1 are clearly noninnocent counterions; so, for the UV-vis titrations, we chose two silver salts that share a sufficient solubility in THF but differ substantially in the bulkiness and geometry of the anion.