Highly stereoselective access to sulfur derivatives starting from zinc organometallics

Synlett

Volumn , Issue 5, 2006, Pages 792-794

  Krasovskiy, Arkady ^a   Gavryushin, Andrey ^a   Knochel, Paul ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

Chirality; Organozinc reagents; Sulfur; Tetramethylthiuram disulfide

Indexed keywords

DITHIOCARBAMIC ACID DERIVATIVE; ORGANOMETALLIC COMPOUND; SULFUR DERIVATIVE; THIRAM; ZINC DERIVATIVE;

ARTICLE; CHEMICAL PROCEDURES; CHEMICAL REACTION; CHEMICAL STRUCTURE; STEREOCHEMISTRY;

EID: 33645380374     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-933117     Document Type: Article

References (18)

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16. This new redox reaction is actively investigated in our laboratories.
17. This lithium salt is readily prepared by treating TMTD (1) in THF with MeLi (1 equiv, -20 °C, 10 min).
18. 2), yielding myrtany dimethyldithiocarbamate as colorless crystals, mp 30-31 °C (70% yield, 673 mg).