Two novel approaches toward stereoselective introduction of β-hydroxymethyl group at the C-7 position of 5-androstene

Synthesis

Volumn , Issue 6, 2006, Pages 975-978

  Gu, Qin ^a   Zheng, Yun Hong ^a   Li, Yuan Chao ^a  

^a SHANGHAI INSTITUTE OF MATERIA MEDICA   (China)

Author keywords

5 androstene; 7 hydroxymethyl; Ionic hydrogenation; Stereoselective; Steroids

Indexed keywords

CARBON; CHEMICAL BONDS; CHLORINE COMPOUNDS; HORMONES; HYDROGENATION; OXIDATION; SILICON;

5-ANDROSTENE; 7Β-HYDROXYMETHYL; IONIC HYDROGENATION; STEREOSELECTIVE; STEROIDS;

STEREOCHEMISTRY;

3BETA,17BETA BIS(TERT BUTYLDIMETHYLSILYLOXY) 5 ANDROSTEN 7 ONE; 3BETA,17BETA BIS(TERT BUTYLDIMETHYLSILYLOXY) 7ALPHA BENZYLOXYMETHYLANDROST 5 EN 7BETA OL; 3BETA,17BETA BIS(TERT BUTYLDIMETHYLSILYLOXY) 7ALPHA HYDROXYMETHYLANDROST 5 EN 7BETA OL; 3BETA,17BETA BIS(TERT BUTYLDIMETHYLSILYLOXY) 7BETA BENZYLOXYMETHYLANDROST 5 EN 7ALPHA OL; 3BETA,17BETA BIS(TERT BUTYLDIMETHYLSILYLOXY) 7BETA HYDROXYMETHYLANDROST 5 EN 7ALPHA OL; 3BETA,17BETA DIHYDROXY 7BETA HYDROXYMETHYLANDROST 5 ENE; ANDROSTANE DERIVATIVE; CARBON; CARBONYL DERIVATIVE; HYDROGEN PEROXIDE; METHYL CHLORIDE; SAMARIUM 153; SILICON; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; DEBENZYLATION; DEOXYGENATION; GRIGNARD REACTION; HYDROGENATION; ISOMER; STEREOCHEMISTRY;

EID: 33645359994     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-926356     Document Type: Article

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