Some thoughts and/or questions about activation energy and pre-exponential factor

Defect and Diffusion Forum

Volumn 249, Issue , 2006, Pages 61-72

  Philibert, J ^a   Klinger, L ^b   Wynblatt, P ^b   Murch, G ^b   Gusak, A ^b  

^a UNIVERSITÉ PARIS SACLAY   (France)

^b NONE

Author keywords

Activation enthalpy; Activation entropy; Arrhenius law; Compensation rule; Meyer Neldel rule; Reaction rate

Indexed keywords

ENTHALPY; ENTROPY; RATE CONSTANTS; THERMODYNAMICS;

ARRHENIUS LAW; COMPENSATION RULE; MEYER-NELDEL RULE; REACTION RATE;

ACTIVATION ENERGY;

EID: 33645359723     PISSN: 10120386     EISSN: 16629507     Source Type: Journal    
DOI: 10.4028/3-908451-17-5.61     Document Type: Conference Paper

References (36)

1. E. Crawford: Arrhenius, from Ionic Theory to the Greenhouse Effect (Science History Publication, USA 1996).
2. S. Arrhenius: Zeit. Phys. Chem. Vol. 4 (1889), p. 226
3. J. Perrin: Les Atomes, First edition, Paris 1912, second ed. (nouvelle redaction), Paris, 1936.
4. S. Glasstone, K.J. Laidler and H. Eyring: The Theory of Rate Processes, Mc Graw Hill (New-York 1941).
5. R.M. Barrer: Diffusion in and through Solids, McMillan (1941)
6. S. Dushman and I. Langmuir: Phys. Rev. Vol. 20 (1922), p. 113
7. I. Langmuir: Phys. Rev. Vol. 22 (1923), p. 357
8. H. Braune: Phys. Chem. Vol. 110 (1924) p. 147
9. J. Van Liempt: Zeit. Phys. Vol. 96 (1935), p. 534
10. C. Wert and C. Zener: Phys. Rev. Vol. 76 (1949), p. 1169
11. C. Zener: J. Appl. Phys. Vol. 22 (1951), p. 372
12. G.H. Vineyard: J. Phys. Chem. Sol. Vol. 3 (1957), p. 121
13. C.P. Flynn: Point Defects and Diffusion (Clarendon Press, Oxford 1972)
14. K.J. Laidler and M.C. King: J. Phys. Chem. Vol. 87 (1983), p. 2657
15. Y.Adda and J. Philibert: La Diffusion dans les Solides, (Presses Universitaires de France, Paris 1966), chapter 8, p. 447 and ff.
16. J F. Gouyet: DIMAT 2000, Def. Diff. Forum, Vol. 194-199 (2001), p. 1
17. J-L. Bocquet, G. Brebec and Y.Limoge: in Physical Metallurgy, Vol 1, Ch.7, Ed. R.W. Cahn and P Haasen (North Holland 1996)
18. A.S. Nowick: J. Appl. Phys. Vol. 22 (1951), p. 1182
19. Y. Limoge and A. Grandjean: Defect Diff. Forum Vol. 143-147 (1997), p. 747
20. R. Kircheim and X.Y. Huang: Phys. Stat. Sol. B Vol. 144 (1987), p. 253
21. B. Lesage and J. Philibert: DIMAT 92, Defect Diff. Forum Vol. 95-98 (1993), p. 1055
22. B. Bokstein: DIMETA 88, Defect Diff. Forum Vol. 66-69 (1989), p. 631
23. W. Lojkowski, D.Beke, J. Kwiecinski, J. Wyrzykowski and M. Grabski: Def. Diff. Forum, Vol. 95-98 (1993), p. 475
24. B. Straumal, B. Bokstein, L.Klinger and L. Shvindlerman: Scripta. Metal. Vol. 15 (1981), p. 1187
25. and B. Straumal, B. Bokstein, L.Klinger and L. Shvindlerman: Scripta. Metal. Vol. 17 (1983), p. 275
26. G. Boisvert, L. Lewis and A. Yelon: Phys. Rev. Lett. Vol. 75 (1995), p. 469
27. A.W. Lawson: J. Chem. Phys. Vol. 32 (1960), p. 131
28. M. Pötnisch and R. Kircheim: Scripta Mat. Vol. 34 (1996), p. 1479
29. A. Yelon and B. Movaghar: Phys. Rev. Lett. Vol. 65 (1990), p. 618
30. G.J. Dienes: J. Appl. Phys. Vol. 21 (1950), p. 1189
31. V.G. Sursaeva, S.G. Protasova and B.B. Straumal: Def. Diff. Forum Vol. 192 (2001), p. 15
32. R.W. Keyes: J. Chem.Phys. Vol. 29 (1958), p. 467
33. Y. Mishin: Diffusion Processes in Advanced Technological Materials, Ed. D. Gupta (Springer, Berlin etc. 2005), p. 141
34. J.L. Bocquet and C. Schmidt: Metallofiz.Noveishie Tekhnol., Vol. 21 (1999), p. 20
35. Atom Movements, ASM Symposium, ASM, Cleveland (1951)
36. th ed. (Butterworth-Heinemann 1998), Chapt. 13, p. 13.