Bridging μη5:η-coordination of an indenyl ligand and reductive coupling of diazabutadienes in the assembly of Di- and tetranuclear mixed-valent ytterbium indenyldiazabutadiene complexes

Chemistry - A European Journal

Volumn 12, Issue 10, 2006, Pages 2752-2757

  Trifonov, Alexander A ^a   Fedorova, Elena A ^a   Fukin, Georgy K ^a   Baranov, Evgenii V ^a   Druzhkov, Nikolai O ^a   Bochkarev, Mikhail N ^a  

^a G A RAZUVAEV INSTITUTE OF ORGANOMETALLIC CHEMISTRY   (Russian Federation)

Author keywords

C H activation; C H coupling; Lanthanides; Mixedvalent compounds; N ligands

Indexed keywords

CHEMICAL REACTIONS; COORDINATION REACTIONS; RARE EARTH ELEMENTS; REDOX REACTIONS; REDUCTION; YTTERBIUM;

C-H ACTIVATION; C-H COUPLING; DIAZABUTADIENE PHN=C(ME)-C(ME)=NPH (DAD); INDENYL LIGAND; MIXEDVALENT COMPOUNDS; N LIGANDS; REDUCTIVE COUPLING;

BUTADIENE;

EID: 33645278647     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200501181     Document Type: Article

References (49)

1. a) H. tom Dieck, I. W. Renk, Chem. Ber. 1971, 104, 110-130
2. b) H. tom Dieck. K.-D. Franz, F. Hoffmann, Chem. Ber. 1975, 108, 163-173
3. c)J. Reinhold, R. Benedix, P. Birner, H. Hennig, Inorg. Chim. Acta 1979, 33, 209-213.
4. a) L. R. Morss, Chem. Rev. 1976, 76, 827-841
5. b) R. G. Finke, S. R. Keenan, D. A. Shirardi, P. L. Watson, Organometallics 1986, 5, 598-601
6. c) A. M. Bond, G. B. Deacon, R. H. Newnham, Organometallics 1986, 5, 2312-2316.
7. M. N. Bochkarev, A. A. Trifonov, F. G. N. Cloke, C. I. Dalby, P. T. Matsunaga, R. A. Andersen, H. Schumann, J. Loebel, H. Hemling, J. Organomet. Chem. 1995, 486, 177-182.
8. a) A. A. Trifonov. E. N. Kirillov, M. N. Bochkarev, H. Schumann, S. Muehle, Russ. Chem. Bull. 1999, 48, 382-384
9. b) A. A. Trifonov, Yu. A. Kurskii, M. N. Bochkarev, S. Muehle, S. Dechert, H. Schumann, Russ. Chem. Bull. 2003, 52, 601-606
10. c) A. A. Trifonov, E. A. Fedorova, G. K. Fukin, V. N. Ikorskii, Yu. A. Kurskii, S. Dechert, H. Schumann, M. N. Bochkarev, Russ. Chem. Bull. 2004, 53, 2736-2743
11. d) A. A. Trifonov, E. A. Fedorova, V. N. Ikorskii, Yu. A. Kurskii, S. Dechert, H. Schumann, M. N. Bochkarev. Eur. J. Inorg. Chem. 2005, 2812-2858.
12. a) M. Schulz, J. M. Boncella, D. J. Berg, T. D. Tilley, R. A. Andersen, Organometallics 2002, 21, 460-472
13. b) D. J. Berg, J. M. Boncella, R. A. Andersen, Organometallics 2002, 21, 4622-4631
14. c) C. J. Kuehl, R. E. Da Re, B. L. Scott, D. E. Morris, K. D. John, Chem. Commun. 2003, 2336-2337
15. d) R. E. Da Re, C.J. Kuehl, M. G. Brown. R. C. Rocha, E. D. Bauer, K. D. John, D. E. Morris, A. P. Shreve, J. L. Sarrao, Inorg. Chem. 2003, 42, 5551-5559.
16. A. A. Trifonov, E. A. Fedorova, G. K. Fukin, N. O. Druzhkov, M. N. Bochkarev, Angew. Chem. 2004, 116, 5155-5158
17. Angew. Chem. Int. Ed. 2004, 43, 5045-5048.
18. W. J. Evans, M. A. Hozbor, J. Organomet, Chem. 1987, 326, 299-306.
19. P. Blagini. G. Lugli, R. Millini, Gazzeta Chim. Italiana 1994, 124, 217-225.
20. a) K. Jonas, W. Rüsseler, C. Krüger, E. Raabe, Angew. Chem. 1986, 98, 905-906
21. Angew. Chem. Int. Ed. Engl. 1986, 25, 928-929
22. b) M. I. Bruce, B. W. Skelton, A. H. White, N. N. Zaitseva, Inorg. Chem. Commun. 1999, 2, 17-20
23. c) S. Sun, C. A. Dullaghan, G. B. Carpenter, A. L. Rieger, P. H. Rieger, D. A. Sweigart. Angew. Chem. 1995, 107, 2734-2737:
24. Angew. Chem. Int. Ed. Engl. 1995, 34, 2540-2542
25. d) A. Eisenstadt, F. Frolow, A. Efraty, J. Chem. Soc. Chem. Commun. 1982, 642-644.
26. a) J. Z. Jin, Z. S. Jin, W. O. Chen, Y. Zhang, Chinese J. Struct. Chem. (Jiegou Huaxue) 1993, 12, 241-245
27. b) H. Schumann, D. Karasiak, S. Muehle, Z. Anorg. Allg. Chem. 2000, 626, 1434-1443
28. c) A. T. Gilbert, B. L. Davis, T. J. Emge, R. D. Broene, Organometallics 1999, 18, 2125-2132.
29. a) Y. Wang, Q. Shen, F. Xue, K. Tu. J. Organomet. Chem. 2000, 598, 359-364
30. b) T. D. Tilley, R. A. Andersen, A. Zalkin, J. Am. Chem. Soc. 1982, 104, 3725-3727
31. c) A. G. Avent. P.B. Hitchkock, A. V. Khvostov. M. F. Lappert, A. V. Protchenko, Dalton Trans. 2003, 1070-1075
32. d) G. B. Deacon, C. M. Forsyth, Chem. Commun. 2002. 2522-2523.
33. For related mixed-valent compounds, see: a) G. B. Deacon, C. M. Forsyth, Chem. Eur. J. 2004, 10, 1798-1804
34. b) G. B. Deacon, A. Gitlits, B. W. Skelton, A. H. White, Chem. Commun. 1999, 1213-1214
35. c) G. B. Deacon, C. M. Forsyth, P. C. Junk, B. W. Skelton, H. White, Chem. Eur. J. 1999, 5, 1452-1459
36. d) M. N. Bochkarev, V. V. Khramenkov, Yu. F. Rad'kov, L. N. Zakharov, J. Organomet. Chem. 1992, 429, 27-39
37. e) C. J. Burns, D. J. Berg, J. Chem. Soc. Chem. Commun. 1987, 272-273
38. f) J. M. Boncella, T. D. Tilley, R. A. Andersen, J. Chem. Soc. Chem. Commun. 1984, 710-712
39. g) C. J. Burns, R. A. Andersen, J. Chem. Soc. Chem. Commun. 1989, 136-137.
40. a) A. A. Trifonov, L. N. Zakharov, M. N. Bochkarev, Yu. T. Struchkov, Izv. Akad. Nauk, Izv. Akad. Nauk Ser. Khim. 1994, 148-151
41. b) H. Göerls, B. Neumueller, A. Scholz, J. Scholz, Angew. Chem. 1995, 107, 732-735
42. Angew. Chem. Int. Ed. Engl. 1995, 34, 673-676.
43. a)C. J. M. Huige, A. L. Spek, Acta Crystallogr. Sect. C 1985, 41, 113-116
44. b)T. V. Laine, M. Klinga, E. Aitola, M. Leskela, Acta Chem. Scand. 1999, 53, 968-973.
45. F. A. Allen, O. Konnard. D. G. Watson, L. Brammer, G. Orpen, R. Taylor, J. Chem. Soc. Perkin Trans. 1 1987, 1-19.
46. A. V. Protchenko, M. N. Bochkarev, Pribory i technika experimenta, Nauka, Moskva, 1990, 1, 194.
47. Bruker (2000) SAINTPlus Data Reduction and Correction Program v. 6.02 a, Bruker AXS, Madison. Wisconsin, USA.
48. G. M. Sheldrick (1998). SADABS v. 2.01, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, Wisconsin, USA.
49. G. M. Sheldrick (2000), SHELXTL v. 6.12, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA.