A novel bi-layered samarium complex with an unprecedented coordination mode of orotic acid [Sm2(HL)2(ox)(H2O) 2]n ·; 2.5nH2O (H3L = orotic acid, ox2- = oxalate2-): Synthesis, crystal structure and physical properties

Inorganic Chemistry Communications

Volumn 9, Issue 4, 2006, Pages 347-350

  Wu, A Qing ^a   Zheng, Fa Kun ^a   Liu, Xi ^a   Guo, Guo Cong ^a   Cai, Li Zhen ^a   Dong, Zhen Chao ^b   Takano, Yoshihiko ^c   Huang, Jin Shun ^a  

^a FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^b UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

^c NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

Author keywords

Crystal structure; Luminescence; Magnetism; Samarium(III) orotate( 2) complex

Indexed keywords

EID: 33645224577     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2005.12.014     Document Type: Article

References (31)

1. G. Biscaro, and E. Belloni Ann. Soc. Chim. Milano XI, fasch I and II 1905
2. G. Biscaro, and E. Belloni Chem. Zentr. [II] 63 1905 64
3. N. Lalioti, C.P. Raptopoulou, A. Terzis, A. Panagiotopoulos, S.P. Perlepes, and E. Manessi-Zoupa J. Chem. Soc., Dalton Trans. 1998 1327
4. H. Schidbaur, H.G. Classen, and J. Helbig Angew. Chem., Int. Ed. Engl. 29 1990 1090
5. T. Solin, K. Matsumoto, and K. Fuwa Bull. Chem. Soc. Jpn. 54 1981 3731
6. K. Matsumoto Inorg. Chim. Acta 151 1998 9
7. O. Kumberger, J. Riede, and H. Schmidbaur Z. Naturforsch. B 48 1993 961
8. O. Kumberger, J. Riede, and H. Schmidbaur Chem. Ber. 124 1991 2739
9. I. Bach, O. Kumberger, and H. Schmidbaur Chem. Ber. 123 1990 2267
10. C.P. Raptopoulou, V. Tangoulis, and V. Psycharis Inorg. Chem. 39 2000 4452
11. X. Li, R. Cao, D.F. Sun, Q. Shi, M.C. Hong, and Y.C. Liang Inorg. Chem. Commun. 5 2002 589
12. D.J. Darensbourg, D.L. Larkins, and J.H. Reibenspies Inorg. Chem. 37 1998 6125
13. S.L. James, D.M.P. Mingos, X.L. Xu, A.J.P. White, and D.J. Williams J. Chem. Soc., Dalton Trans. 1998 1335
14. T.W. Hambley, R.I. Christopherson, and E.S. Zvargulis Inorg. Chem. 34 1995 6550
15. M.J. Plater, M.R.St.J. Foreman, J.M.S. Skakle, and R.A. Howie Inorg. Chem. Acta 332 2002 135
16. S. Bekiroglu, and O. Kristiansson J. Chem. Soc., Dalton Trans. 2002 1330
17. I. Mutikainen, R. Hamalainen, M. Klinga, and U. Turoeinen Z. Kristallogr. 212 1997 65
18. X. Li, R. Cao, D.F. Sun, Q. Shi, W.H. Bi, and M.C. Hong Inorg. Chem. Commun. 6 2003 815
19. D.J. Darensbourg, J.D. Fraper, D.L. Larkins, B.J. Frost, and J.H. Reibenspies Inorg. Chem. 37 1998 6125
20. M. Rul, K. Wels, and H. Vahrenkamp J. Am. Chem. Soc. 36 1997 2130
21. X. Li, Q. Shi, D.F. Sun, W.H. Bi, and R. Cao Eur. J. Inorg. Chem. 2004 2747
22. -1): 3425(s), 1693(s), 1598(vs), 1495(w), 1412(s), 1338(m), 1313(m), 1012(w), 816(w). X-ray diffraction data were collected on a Siemens Smart CCD diffractometer equipped with graphite-monochromated Mo Kα radiation (λ = 0.71073 Å). Absorption correction was performed by the SADABS program. The structure was solved by the direct methods and subsequent difference Fourier syntheses. All non-hydrogen atoms were refined anisotropically. Hydrogen atoms of water molecules were located in difference Fourier syntheses and refined isotropically with O-H = 0.86 Å and U(H) = 1.2 U(O). The remaining hydrogen atoms were added according to theoretical models, assigned isotropic thermal parameters and allowed to ride on their respective parent C atoms before the final cycle of full-matrix least-squares refinement.
23. M. Hernandez-Molina, P.A. Lorenzo-Luis, and C. Ruiz-Perez Cryst. Eng. Commun. 3 2001 60
24. G. Zucchi, R. Scopelliti, and J.C.G. Bünzli J. Chem. Soc., Dalton Trans. 2001 1975
25. S. Petoud, S.M. Cohen, J.-C.G. Bünzli, and K.N. Raymond J. Am. Chem. Soc. 125 2003 13324
26. W.Y. Yang, L. Chen, and S. Wang Inorg. Chem. 40 2001 507
27. H. Schidbaur, H.G. Classen, and J. Helbig Angew. Chem., Int. Ed. Engl. 29 1990 1090
28. M. Bruchez Jr., M. Moronne, P. Gin, S. Weiss, and A.P. Alivisatos Science 281 1998 2013
29. E. Spodine, Y. Moreno, M.T. Garland, O. Pena, and R. Baggio Inorg. Chim. Acta 309 2000 57
30. A. Herpin Theorie de Magnetism 1968 Presses Universitaires de France Paris
31. M.L. Kahn, C. Mathoniere, and O. Kahn Inorg. Chem. 38 1999 3692