Modelling of the extraction and back-extraction equilibria of zinc from spent pickling solutions

Separation Science and Technology

Volumn 41, Issue 4, 2006, Pages 757-769

  Samaniego, Henar ^a   Fresnedo San Roman, M ^a   Ortiz, Inmaculada ^a  

^a UNIVERSITY OF CANTABRIA   (Spain)

Author keywords

Back extraction; Extraction equilibrium; Tributyl phosphate; Water; Zinc chloride

Indexed keywords

COMPOSITION; MATHEMATICAL MODELS; REACTION KINETICS; SOLUTIONS; WATER; ZINC;

BACK EXTRACTION; EXTRACTION EQUILIBRIUM; TRIBUTYL PHOSPHATE; ZINC CHLORIDE;

EXTRACTION;

COMPOSITION; EXTRACTION; MATHEMATICAL MODELS; REACTION KINETICS; SOLUTIONS; WATER; ZINC;

ABSORPTION ISOTHERM; EXTRACTION METHOD; MATHEMATICAL MODEL;

EID: 33644986905     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496390600552289     Document Type: Article

References (18)

1. Jha, M.K., Kumar, V., and Singh, R.J. (2002) Solvent extraction of zinc from chloride solutions. Solvent Extraction and Ion Exchange, 20 (3): 389-405.
2. Ortiz, I., Bringas, E., San Román, M.F., and Urtiaga, A.M. (2004) Selective separation of zinc and iron from spent pickling solutions by membrane-based solvent extraction: process viability. Separation Science & Technology, 39 (0): 1-15.
3. Regel, M., Sastre, A.M., and Szymanowski, J. (2001) Recovery of zinc(II) from HC1 spent pickling solutions by solvent extraction. Environmental Science & Technology, 35: 630-635.
4. Kirschling, P., Nowak, K., Miessiac, I., Nitsch, W., and Szymanowsky, J. (2001) Membrane extraction-stripping process for zinc(ii) recovery from HCL solution. Solvent Extraction Research and Development, 8: 135-143.
5. Cierpezewski, R., Miesiac, I., Regel-Rosocka, M., Sastre, A.M., and Szymanowki, J. (2002) Removal of zinc (II) from spent hydrochloric acid solutions from zinc hot galvanizing plants. Industrial & Engineering Chemistry Research, 41: 598-603.
6. Mishonov, I.V., Alejski, K., and Szymanowski, J. (2004) A contributive study on the stripping of zinc (11) from loaded TBP using an ammonia/ammonium chloride solution. Solvent Extraction and Ion Exchange, 22 (2): 219-241.
7. Galan, B., Urtiaga, A.M., Alonso, A.I., Irabien, A., and Ortiz, M.I. (1994) Extraction of anions with aliquat 336: chemical equilibrium modeling. Industrial & Engineering Chemistry Research, 22: 1765-1770.
8. Ortiz, I. and San Roman, M.F. (2002) Analysis of the back-extraction of cadmium-nickel-D2EHPA organic phases. Separation Science and Technology, 37 (3): 607-625.
9. Urtiaga, A., Abellán, M.J., Irabien, J.A., and Ortiz, I. (2005) Membrane contactors for the recovery of metallic compounds, modelling of copper recovery from WPO processes. Journal of Membrane Science, 257 (1-2): 161-170.
10. Dimitrov, K., Alexandrova, S., Sabomi, A., Debay, E., and Boyadzhiev, L. (2002) Recovery of zinc from chloride media by batch pertraction in a rotating film contactor. Journal of Membrane Science, 207: 119-127.
11. Alonso, A.I., Galan, B., Irabien, A., and Ortiz, I. (1997) Separation of Cr(VI) with Aliquat 336: Chemical equilibrium modeling. Separation Science and Technology, 32 (9): 1543-1555.
12. Galan, B., San Roman, F., Irabien, A., and Ortiz, I. (1998) Viability of the Separation of Cd from highly concentrated Ni-Cd mixtures by non dispersive solvent extraction. Chemical Engineering Journal, 70: 237-243.
13. Niemczewska, J., Cierpiszewski, R., and Szymanowski, J. (2004) Mass transfer of zinc(II) extraction from hydrochloric acid solution in the Lewis cell. Desalination. Desalination, 162: 169-177.
14. Sanad, W., Flex, H., and Marei, S.A. (1993) Kinetics of zinc(II) chloride extraction with tributy 1 phospate. Journal of Radionalytical and Nuclear Chemistry, 170 (1): 253-241.
15. Forrest, V.M.P., Scargill, D., and Spickernell, D.R. (1969) The extraction of zinc and cadmium by tri-n-butyl phosphate from aqueous chloride solutions. Journal of Inorganic & Nuclear Chemistry, 31: 187-197.
16. Morris, D.F.C. and Short, E.L. (1962) Zinc chloride and zinc bromide complexes. Part II. Solvent-extraction studies with zinc-65 as tracer. Journal of the Chemical Society, Abstracts (1962) 2662-2671.
17. Bogacki, M.B., Zhikova, S., Kyuchoukov, G., and Szymanowski, J. (1994) Modeling of copper(II) and zinc(II) extraction from chloride media with Kelex 100. Plants. Industrial & Engineering Chemistry Research, 39: 740-745.
18. Miesiac, I. and Szymanwski, J. (2004) Separation of Zinc(II) from Hydrochloric Acid Solutions in a Double Lewis Cell. Solvent Extracion and Ion Exchange, 2: 243-265.