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33644967106
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-
note
-
13C NMR spectra shown in Fig. 6, a chemical shift drift is estimated to be 0.0047 ppm during the measurements. This order of the drift does not significantly affect the chemical shift values of the respective components that are listed in Tables 3 and 4.
-
-
-
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22
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33644983727
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note
-
The isotropic chemical shifts calculated from the first moment [24] of the CSA spectra for the non-crystalline and the fast all-trans components in DPE9 are 30.94 and 33.24 ppm, respectively. The isotropic chemical shift of the latter component is very close to that observed in the corresponding MAS spectrum (33.25 ppm). Since the shape of the non-crystalline peak in the MAS spectrum is not symmetric like a Lorentzian, its top position cannot be simply compared with the 30.94 ppm calculated above.
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-
-
-
23
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33644990237
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-
note
-
The isotropic chemical shifts calculated from the first moment of the CSA spectra for the non-crystalline and the fast all-trans components in DPE16 are 30.67 and 32.01 ppm, respectively. The value estimated for the fast all-trans is slightly different from its chemical shift of 33.25 ppm obtained under MAS. This disagreement may be due to macroscopic anisotropy that will still exist for the sample packed in a MAS rotor after cutting into small pieces in the case of higher-level drawing.
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30
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0032155303
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P.G. Klein, M.B. Robertson, M.A.N. Driver, I.M. Ward, and K.J. Packer Polym Int 47 1998 76
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32
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34
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0035908150
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Y. Bin, L. Ma, R. Adachi, H. Kurosu, and M. Matsuo Polymer 42 2001 8125
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39
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33644983975
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Nishimura T, Kaji H, Horii F; to be published
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Nishimura T, Kaji H, Horii F; to be published.
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