One-pot synthesis of 1,4,7,10,13,16,21,24-octaazabicyclo[8.8.8]hexacosane - The peraza analogue of [2.2.2]cryptand

Synthesis

Volumn , Issue 5, 2006, Pages 759-761

  Redko, Mikhail Yurievich ^a   Huang, Rui ^a   Dye, James Louis ^a   Jackson, James Edward ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

Complexant; Imines; Macropolycyclic; Polyamine; Sodium

Indexed keywords

CONDENSATION; POLYETHYLENES; REDUCTION; SYNTHESIS (CHEMICAL);

COMPLEXANT; IMINES; MACROPOLYCYCLIC; POLYAMINE;

ORGANIC ACIDS;

1,4,7,10,13,16,21,24 OCTAAZABICYCLO[8.8.8]HEXACOSANE; 2 PROPANOL; AMINE; GLYOXAL; HETEROCYCLIC COMPOUND; POLYETHER DERIVATIVE; TRIS (2 AMINOETHYL)AMINE; UNCLASSIFIED DRUG;

ARTICLE; DECOMPOSITION; POLYMERIZATION; REDUCTION; SYNTHESIS;

EID: 33644931314     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-926335     Document Type: Article

References (36)

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2. -) or a trapped electron.
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36. An anonymous reviewer has kindly offered the following suggestion: 'As source of glyoxal for the Schiff-base condensation, some workers use the trimeric solid, which is depolymerized by reflux for 15 mins or so in the intended alcohol: perhaps the new synthesis of 2 could be extended to include this route to the starting dialdehyde, which might indeed present less hazard than the 40% aqueous solution which is described.' Though we have not tested this suggestion, it appears sensible and we include it here for completeness.