Convenient titration method for organometallic zinc, magnesium, and lanthanide reagents

Synthesis

Volumn , Issue 5, 2006, Pages 890-891

  Krasovskiy, Arkady ^a   Knochel, Paul ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

Lithium chloride; Magnesium reagents; Organolanthanide reagents; Titration; Zinc reagents

Indexed keywords

LITHIUM COMPOUNDS; MAGNESIUM PRINTING PLATES; ORGANOMETALLICS; SOLUTIONS; ZINC;

LITHIUM CHLORIDE; MAGNESIUM REAGENTS; ORGANOLANTHANIDE REAGENTS; ZINC REAGENTS;

TITRATION;

LANTHANIDE; MAGNESIUM; ORGANOMETALLIC COMPOUND; REAGENT; ZINC;

ARTICLE; REACTION ANALYSIS; TITRIMETRY;

EID: 33644924126     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-926345     Document Type: Article

References (21)

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21. It is possible to determine the concentration of most organolithium compounds using our procedure with the exception of some secondary and tertiary alkyl lithiums in which a facile elimination of HI from the alkyl iodide formed during titration is possible (for example s-BuLi and t-BuLi).