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Volumn 25, Issue 5, 2006, Pages 1321-1324

Orthometalation of Tp*Rh(PPh3)2: Implications for catalytic reactivity

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; DECOMPOSITION; SOLVENTS; THERMAL EFFECTS;

EID: 33644896522     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0510268     Document Type: Article
Times cited : (15)

References (59)
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    • For reviews of scorpionate complexes, see: (b) Trofimenko, S. Chem. Rev. 1993, 93, 943-980.
    • (1993) Chem. Rev. , vol.93 , pp. 943-980
    • Trofimenko, S.1
  • 12
    • 33644896013 scopus 로고    scopus 로고
    • Ph.D. Thesis, University of Sevilla
    • Dimerization of terminal alkynes and hydrosilylation of ethylene: Trujillo, M. Ph.D. Thesis, University of Sevilla, 1999.
    • (1999)
    • Trujillo, M.1
  • 50
    • 1842528347 scopus 로고    scopus 로고
    • i-pr2Rh(dppe) [dppe = 1,2-bis(diphenylphos-phino)ethane], undergoes phosphine oxidation with Ch, followed by orthometalation to the corresponding five-membered ring complex. Takahashi, Y.; Hashimoto, M.; Hikichi, S.; Moro-oka, Y.; Akita, M. Inorg. Chim. Acta 2004, 357, 1711-1724.
    • (2004) Inorg. Chim. Acta , vol.357 , pp. 1711-1724
    • Takahashi, Y.1    Hashimoto, M.2    Hikichi, S.3    Moro-Oka, Y.4    Akita, M.5
  • 53
    • 33644898885 scopus 로고    scopus 로고
    • note
    • 3. Formation of both 3 and 4 were accompanied by orthometalation. The X-ray structures of 3 and 4 bear a close resemblance to structures of the related complexes reported by Carlton and are presented in the Supporting Information.
  • 54
    • 0038786857 scopus 로고    scopus 로고
    • 3 ligand, a few were found to have been formed irreversibly. For examples, see: (a) Feldman, J. D.; Peters, J. C.; Tilley, T. D. Organometallics 2002, 21, 4050-4064.
    • (2002) Organometallics , vol.21 , pp. 4050-4064
    • Feldman, J.D.1    Peters, J.C.2    Tilley, T.D.3
  • 55
    • 33644899729 scopus 로고    scopus 로고
    • Ref 14
    • (b) Ref 14.
  • 56
    • 33644930046 scopus 로고    scopus 로고
    • For an example of reversible orthometalation, see ref 11f
    • For an example of reversible orthometalation, see ref 11f.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.