Crystallochemistry and structural studies of two newly CaSb0.50 Fe1.50 (PO4)3 and Ca0.50 SbFe (PO4)3 Nasicon phases

Powder Diffraction

Volumn 21, Issue 1, 2006, Pages 45-51

  Aatiq, Abderrahim ^a   Tigha, My Rachid ^a   Hassine, Rabia ^a   Saadoune, Ismael ^b  

^a FACULTÉ DES SCIENCES BEN M SIK   (Morocco)

^b Centre d'Excellence de Recherche sur les Matáriaux CERM   (Morocco)

Author keywords

Antimony and iron phosphate; Nasicon structure; Rietveld refinement; X ray diffraction

Indexed keywords

CRYSTALLOCHEMISTRY; CRYSTALLOGRAPHIC STRUCTURE; IRON PHOSPHATES; NASICON STRUCTURE; RANDOMLY DISTRIBUTED; SOLID-STATE REACTION TECHNIQUES; STRUCTURAL STUDIES; STRUCTURE REFINEMENTS;

ANTIMONY COMPOUNDS; CALCIUM; RIETVELD ANALYSIS; RIETVELD REFINEMENT; SINGLE CRYSTALS; SOLID STATE REACTIONS; VACANCIES; X RAY DIFFRACTION; X RAY POWDER DIFFRACTION;

IRON COMPOUNDS;

EID: 33644778752     PISSN: 08857156     EISSN: 19457413     Source Type: Journal    
DOI: 10.1154/1.2104535     Document Type: Article

References (21)

1. Aatiq, A. (2004). " Synthesis and structural characterization of ASnFe (PO4) 3 (A= Na2, Ca, Cd) phosphates with the Nasicon type structure., " Powder Diffr. 19, 272-279.
2. Aatiq, A. and Dhoum, H. (2004). " Structure of AFeTi (PO4) 3 (A=Ca, Cd) Nasicon phases from powder X-ray data., " Powder Diffr. 19, 157-161.
3. Aatiq, A., Hassine, R., Tigha, R., and Saadoune, I. (2005). " Structures of two newly synthesized A0.50 SbFe (PO4) 3 (A=Mn, Cd) Nasicon phases., " Powder Diffr. 20, 33-39.
4. Aatiq, A., Mánátrier, M., Croguennec, L., Suard, E., and Delmas, C. (2002). " On the structure of Li3 Ti2 (PO4) 3., " J. Mater. Chem. 12, 2971-2978.
5. Aatiq, A., Mánátrier, M., El Jazouli, A., and Delmas, C. (2002). " Structural and lithium intercalation studies of Mn(0.5-x) Cax Ti2 (PO4) 3 phases (0≤x≤0.50)., " Solid State Ionics 150, 391-405.
6. Brown, I. D. and Altermatt, D. (1985). " Bond-valence parameters obtained from a systematic analysis of the inorganic crystal structure database., " Acta Crystallogr., Sect. B: Struct. Sci. 41, 244-247.
7. Cherkaoui, F., Viala, J. C., Delmas, C., and Hagenmuller, P. (1986). " Crystal chemistry and ionic conductivity of a new Nasicon-related solid solution Na1+x Zr2-x2 Mgx2 (PO4) 3., " Solid State Ionics 21, 333-337.
8. Delmas, C., Viala, J. C., Olazcuaga, R., Le Flem, G., Hagenmuller, P., Cherkaoui, F., and Brochu, R. (1981). " Ionic conductivity in Nasicon-type phases Na1+x Zr2-x Lx (PO4) 3 (L=Cr, In, Yb)., " Solid State Ionics 3/4, 209-214.
9. Hagman, L. and Kierkegaard, P. (1968). " The crystal structure of NaMe2IV (PO4) 3; Me=Ge, Ti, Zr., " Acta Chem. Scand. (1947-1973) 22, 1822-1932.
10. Hong, H. Y. -P. (1976). " Crystal structures and crystal chemistry in the system Na(1+x) Zr2 Six P(3-x) O12., " Mater. Res. Bull. 11, 173-182.
11. Krimi, S., Mansouri, I., El Jazouli, A., Chaminade, J. P., Gravereau, P., and Le Flem, G. (1993). " The structure of Na5 Ti (PO4) 3., " J. Solid State Chem. 105, 561-566.
12. Limaye, S. Y., Agrawal, D. K., and McKinstry, H. A. (1987). " Synthesis and thermal expansion of MZr4 P6 O24 (M=Mg, Ca, Sr, Ba)., " J. Am. Ceram. Soc. 70, 232-236.
13. Masquelier, C., Wurn, C., Rodriguez-Carvajal, J., Gaubicher, J., and Nazar, L. F. (2000). " A powder neutron diffraction investigation of the two rhombohedral Nasicon analogues: γ - Na3 Fe2 (PO4) 3 and Li3 Fe2 (PO4) 3., " Chem. Mater. 12, 525-532.
14. Nanjundaswamy, K. S., Padhi, A. K., Goodenoogh, J. B., Okada, S., Ohtsuka, H., Arai, H., and Yamaki, J. (1996). " Synthesis, redox potential evaluation and electrochemical characteristics of Nasicon-related-3D framework compounds., " Solid State Ionics 92, 1-10.
15. Padhi, A. K., Nanjundaswamy, K. S., Masquelier, C., and Goodenoogh, J. B. (1997). " Mapping of transition metal redox energies in phosphates with Nasicon structure by lithium intercalation., " J. Electrochem. Soc. 144, 2581-2586.
16. Pikl, R., De Waal, D., Aatiq, A., and El Jazouli, A. (1998). " Vibrational spectra and factor group analysis of Mn(0.5+x) Ti(2-2x) Cr2x (PO4) 3 (0≤x≤0.5)., " Vib. Spectrosc. 16, 137-143.
17. Rodriguez-Carvajal, J. (1997). "Fullprof, Program for Rietveld refinement," Laboratoire Láon Brillouin (CEA-CNRS) Saclay, France.
18. Roy, R., Vance, E. R., and Alamo, J. (1982). " [NZP], A new radiophase for ceramic nuclear waste forms., " Mater. Res. Bull. 17, 585-589.
19. Serghini, A., Brochu, R., Olazcuaga, R., and Gravereau, R. (1995). " The monovalent copper tin phosphate CuSn2 (PO4) 3., " Mater. Lett. 22, 149-153.
20. Shannon, R. D. (1976). " Revised effective ionic and systematic studies of interatomic distances in halides and chalcogenides., " Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. A32, 751-767.
21. Yin, S. C., Grondey, H., Strobel, P. S., and Nazar, L. F. (2004). Li2.5 V2 (PO4) 3: A room-temperature analogue to the fast-ion conducting high-temperature γ -phase of Li3 V2 (PO4), " Chem. Mater. 16, 1456-1465.