Optimisation and application of polyolefin branch quantification by melt-state13C NMR spectroscopy

Macromolecular Chemistry and Physics

Volumn 207, Issue 4, 2006, Pages 382-395

  Klimke, Katja ^a   Parkinson, Matthew ^a   Piel, Christian ^b   Kaminsky, Walter ^b   Spiess, Hans Wolfgang ^a   Wilhelm, Manfred ^a,c  

^a MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

^b UNIVERSITY OF HAMBURG   (Germany)

^c DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

Branch; Melt; NMR; Polyethylene; Quantification

Indexed keywords

MONOMERS; NUCLEAR MAGNETIC RESONANCE; POLYETHYLENES; POLYPROPYLENES; SIGNAL TO NOISE RATIO;

LONG-CHAIN BRANCH (LCB); QUANTIFICATION; SHORTCHAIN BRANCHING (SCB);

POLYOLEFINS;

EID: 33644647742     PISSN: 10221352     EISSN: 15213935     Source Type: Journal    
DOI: 10.1002/macp.200500422     Document Type: Article

References (53)

1. H. H. Brintzinger, D. Fischer, R. Mulhaupt, B. Rieger, R. Waymouth, Angew. Chem. Int. Ed. Engl. 1995, 34, 1143.
2. E. Kokko, A. Malmberg, P. Lehmus, B. Löfgren, J. Seppälä, J. Polym. Sci., Part A: Polym. Chem. 2000, 38, 376.
3. W. Wang, S. Zhu, S. Park, Macromolecules 2000, 33, 5770.
4. W. Kaminsky, Adv. Catal. 2001, 46, 89.
5. E. Kokko, P. Lehmus, A. Malmberg, B. Löfgren, J. Seppälä, "Long-Chain Branched Polyethene via Metallocene-Catalysis: Comparison of Catalysts", in: Organometallic Catalyst and Olefin Polymerization, Catalysts for a New Millennium, Springer, Berlin 2001, pp. 335-345.
6. G. B. Galland, R. Quijada, R. Rojas, G. Bazan, Z. J. A. Komon, Macromolecules 2002, 35, 339.
7. C. Capacchione, A. Proto, J. Okuda, J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 2815.
8. L. G. Furlan, F. A. Kunrath, R. S. Mauler, R. F. de Souza, O. L. C. Casagrande, Jr., J. Mol. Catal. A: Chem. 2004, 214, 207.
9. L. Izzo, L. Caporaso, G. Senatore, L. Oliva, Macromolecules 1999, 32, 6913.
10. P. Lehmus, E. Kokko, R. Leino, H. J. G. Luttikhedde, B. Rieger, J. V. Seppala, Macromolecules 2000, 33, 8534.
11. M. H. Prosenc, H. H. Brintzinger, Organometallics 1997, 16, 3889.
12. K. Thorshaug, J. A. Stovneng, E. Rytter, M. Ystenes, Macromolecules 1998, 31, 7149.
13. M. Zhang, S. E. Wanke, Polym. Eng. Sci. 2003, 43, 1878.
14. P. M. Wood-Adams, J. M. Dealy, A. W. deGroot, O. D. Redwine, Macromolecules 2000, 33, 7489.
15. R. N. Shroff, H. Mavridis, Macromolecules 2001, 34, 7362.
16. R. Shroff, A. Prasad, C. Lee, J. Polym. Sci., Part B: Polym. Phys. 1996, 34, 2317.
17. F. A. Bovey, F. C. Schilling, F. L. McCrackin, H. L. Wagner, Macromolecules 1976, 9, 76.
18. D. C. Bugada, A. Rudin, Eur. Polym. J. 1987, 23, 847.
19. A. M. Striegel, M. R. Krejsa, J. Polym. Sci., Part B: Polym. Phys. 2000, 38, 3120.
20. J. F. Vega, A. Santamaria, A. Muñoz-Escalona, P. Lafuente, Macromolecules 1998, 31, 3639.
21. R. N. Shroff, H. Mavridis, Macromolecules 1999, 32, 8454.
22. P. M. Wood-Adams, J. Rheol. 2001, 45, 203.
23. D. J. Lohse, S. T. Milner, L. J. Fetters, M. Xenidou, N. Hadjichristidis, R. A. Mendelson, C. A. Garcia-Franco, M. K. Lyon, Macromolecules 2002, 35, 3066.
24. C. Gabriel, H. Münstedt, Rheol. Acta 2002, 41, 232.
25. C. Gabriel, J. Kaschta, H. Münstedt, Rheol. Acta 1998, 37, 7.
26. B. J. Crosby, M. Mangnus, W. de Groot, R. Daniels, T. C. B. McLeish, J. Rheol. 2002, 46, 401.
27. S. Trinkle, P. Walter, C. Friedrich, Rheol. Acta 2002, 41, 103.
28. F. A. Bovey, P. A. Mirau, "NMR of Polymers", Academic Press, San Diego 1996.
29. G. A. Morris, Magn. Reson. Chem. 1986, 24, 371.
30. W. Liu, D. G. Ray, P. Rinaldi, Macromolecules 1999, 32, 3817.
31. M. R. Seger, G. E. Maciel, Anal. Chem. 2004, 76, 5734.
32. R. C. Zeigler, Macromol. Symp. 1994, 86, 213.
33. 13C NMR Study of Linear Low-Density Polyethylene", in: Olefin Polymerization, Emerging Frontiers, Symposium Book Series, vol. 749, ACS 2000, pp. 163-176.
34. A. Pines, M. G. Gibby, J. S. Waugh, J. Chem. Phys. 1972, 56, 1776.
35. D. E. Axelson, "Carbon-13 Solid-State NMRof Semicrystalline Polymers", in: High Resolution NMR Spectroscopy of Synthetic Polymers in Bulk, VCH Publishers Inc., Deefield Beach, FL 1986, pp. 157-226.
36. M. Pollard, K. Klimke, R. Graf, H. W. Spiess, M. Wilhelm, O. Sperber, C. Piel, W. Kaminsky, Macromolecules 2004, 37, 813.
37. J. J. Dechter, R. A. Komoroski, D. E. Axelson, L. M. Mandelkern, J. Polym. Sci., Part B: Polym. Phys. 1981, 19, 631.
38. G. R. Hatfield, W. E. Killinger, R. C. Zeigler, Anal. Chem. 1995, 67, 3082.
39. V. M. Litvinov, V. B. F. Mathot, Solid State Nucl. Magn. Reson. 2002, 22, 218.
40. K. Thakur, "High-Temperature Solid-State NMR of Cross-Linked, Insoluble, and Unswellable Polymers", in: NMR Spectroscopy of Polymers in Solution and in the Solid State, ACS Symposium Book Series, vol. 834, ACS 2003, pp. 32-42.
41. J. V. Prasad, P. V. C. Rao, V. N. Garg, Eur. Polym. J. 1991, 27, 251.
42. M. Parkinson, K. Klimke, C. Piel, W. Kaminsky, H. W. Spiess, M. Wilhelm, "Effect of Branch Length on NMR Relaxation Properties in Molten Polyethylene-co-α-Olefins", 2006 (in preparation).
43. W. Kaminsky, C. Piel, K. Scharlach, Macromol. Symp. 2005, 226, 25.
44. F. J. Stadler, C. Piel, K. Klimke, J. Kaschta, M. Parkinson, W. Kaminsky, M. Wilhelm, H. Münstedt, Macromolecules 2005 (in press).
45. R. Quijada, A. Narvaez, R. Rojas, F. M. Rabagliati, G. Barrera-Galland, R. Santos-Mauler, R. Benavente, E. Pérez, J. M. Pereña, A. Bello, Macromol. Chem. Phys. 1999, 200, 1306.
46. G. A. Morris, R. Freeman, J. Am. Chem. Soc. 1979, 101, 760.
47. D. M. Doddrell, D. T. Pegg, M. R. Bendall, J. Magn. Res. 1982, 48, 323.
48. G. Bodenhausen, R. Freeman, G. A. Morris, D. L. Turner, J. Magn. Res. 1917, 28, 17.
49. L. Muller, A. Kumar, R. R. Ernst, J. Magn. Res. 1977, 25, 383.
50. J. C. Randall, JMS-Rev. Macromol. Chem. Phys. 1989, C29, 201.
51. A. J. Shaka, J. Keeler, T. Frenkiel, R. Freeman, J. Magn. Res. 1983, 52, 335.
52. A. J. Shaka, J. Keeler, R. Freeman, J. Magn. Res. 1983, 53, 313.
53. M. D. Pooter, P. Smith, K. K. Dohrer, K. F. Bennett, M. D. Meadows, C. G. Smith, H. P. Schouwenaars, R. A. Geerards, J. Appl. Polym. Sci. 1991, 42, 399.