Selective hydrogenation of α,β-unsaturated oxosteroids with homogeneous rhodium catalysts

Journal of Molecular Catalysis A: Chemical

Volumn 247, Issue 1-2, 2006, Pages 275-282

  Nunes, Rui M D ^a   Peixoto, Andreia F ^a   Axet, M Rosa ^b   Pereira, Mariette M ^a   Moreno, Maria José ^c   Kollár, László ^d   Claver, Carmen ^b   Castillón, Sergio ^b  

^a UNIVERSITY OF COIMBRA   (Portugal)

^b UNIVERSITAT ROVIRA I VIRGILI   (Spain)

^c UNIVERSITY OF COIMBRA   (Portugal)

^d UNIVERSITY OF PÉCS   (Hungary)

Author keywords

Hydrogenation; Oxosteroid; Phosphine; Phosphite; Rhodium; Steroid

Indexed keywords

CARBON MONOXIDE; CATALYST ACTIVITY; HYDROGENATION; PHOSPHORUS; RHODIUM;

OXOSTEROID; PHOSPHINE; SELECTIVE HYDROGENATION; STEROID;

UNSATURATED COMPOUNDS;

EID: 33644601080     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2005.11.058     Document Type: Article

References (28)

1. J. Fried, and J.A. Edwards Organic Reactions in Steroid Chemistry vol. I 1972 Van Nostrand Reinhold Company New York pp. 111-144
2. C. Djerassi Steroid Reactions: An Outline for Organic Chemists 1963 Holden-Day Inc. San Francisco
3. L. Kollár, S. Tôrös, B. Heil, and Z. Tuba J. Mol. Catal. 47 1988 33
4. G.J.H. Buisman, M.E. Martin, E.J. Vos, A. Kootwijt, P.C.J. Kamer, and P.W.N.M. van Leeuwen Tetrahedron Asymm. 6 1995 719
5. R. Axet, C. Claver, S. Castillón, in preparation.
6. M. Aghmiz, A. Aghmiz, Y. Díaz, A. Masdeu-Bultó, C. Claver, and S. Castillón J. Org. Chem. 69 2004 7502
7. E. Guiu, M. Aghmiz, Y. Díaz, C. Claver, B. Meseguer, C. Militzer, S. Castillón, Eur. J. Org. Chem., in press.
8. G.J.H. Buisman, P.C.J. Kamer, and P.W.N.M. van Leeuwen Tetrahedron Asymm. 4 1993 1625
9. P.W.N.M. van Leeuwen, and C.F. Roobeek J. Organomet. Chem. 258 1983 343
10. R. Uson, L.A. Oro, and J.A. Cabeza Inorg. Synth. 23 1985 126
11. H. Burrows M.M. Pereira Síntese e Estrutura 2005 Escolar Editora Lisboa
12. Dictionary of Organic Compounds vol. 1 1936 Eyre and Spottiswoode Publishers London pp. 232-233
13. Dictionary of Organic Compounds, vol. 1, Eyre and Spottiswoode Publishers Ltd., London, 1953.
14. S. Tórös, L. Kollár, B. Heil, and L. Markó J. Organomet. Chem. 255 1983 377
15. S. Deerenberg, O. Pàmies, M. Diéguez, C. Claver, P.C.J. Kramer, and P.W.N.M. van Leeuwen J. Org. Chem. 66 2001 7626
16. O. Pàmies, M. Diéguez, G. Net, A. Ruiz, and C. Claver J. Org. Chem. 66 2001 8364
17. R.S. Dickson Homogeneous Catalysis with Compounds of Rhodium and Iridium 1985 D. Reidel Publishing Company Dordrecht pp. 43-44
18. W. Voelter, and C. Djerassi Chem. Ber. Recueil 101 1968 58
19. C. Djerassi, and J. Gutzwiller J. Am. Chem. Soc. 88 1966 4537
20. A.J. Birch J. Chem. Soc. (C) 1966 1894
21. R. Skoda-Földes, and L. Kollár Chem. Rev. 103 2003 4095
22. A. Wilds, and C. Djerassi J. Am. Chem. Soc. 68 1946 1712
23. A. Ryer, W. Gebert, and N. Murril J. Am. Chem. Soc. 72 1950 4247
24. D.L. Dubois, and D.W. Meek Inorg. Chim. Acta 19 1976 L29
25. J. Niewahner, and D.W. Meek Adv. Chem. Ser. 196 1982 257
26. J. Niewahner, and D.W. Meek Inorg. Chim. Acta 64 1982 L123
27. R.H. Crabtree The Organometallic Chemistry of the Transition Metals 1988 John Wiley & Sons New York
28. P.W.N.M. van Leeuwen Homogeneous Catalysis - Understanding the Art 2004 Kluwer Academic Publishers Dordrecht pp. 11, 75-77