Kinetics and mechanism of acid-catalyzed hydrolysis of the diazo functional groups of 1-diazo-2-indanone and 2-diazo-1-indanone in aqueous solution

Canadian Journal of Chemistry

Volumn 83, Issue 9, 2005, Pages 1202-1206

  Chiang, Yvonne ^a   Kresge, A Jerry ^a   Sadovski, Oleg ^a   Zeng, Xiaofeng ^a   Zhu, Yu ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

Acid catalysis; Buffer catalysis saturation; Diazo compound hydrolysis; Solution kinetics; Solvent isotope effects

Indexed keywords

CATALYSIS; ISOTOPES; KETONES; REACTION KINETICS; SOLUTIONS; SOLVENT EXTRACTION;

ACID CATALYSIS; BUFFER CATALYSIS SATURATION; DIAZO COMPOUND HYDROLYSIS; SOLUTION KINETICS; SOLVENT ISOTOPE EFFECTS;

HYDROLYSIS;

1 DIAZO 2 INDANONE; 1 HYDROXY 2 INDANONE; 2 DIAZO 1 INDANONE; BUFFER; DEUTERIUM OXIDE; FORMIC ACID; HYDROGEN; INDANONE DERIVATIVE; NITROGEN; PERCHLORIC ACID; SOLVENT; UNCLASSIFIED DRUG; WATER;

AQUEOUS SOLUTION; ARTICLE; ATOM; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CATALYST; DENSITY; HYDROLYSIS; KINETICS; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REACTION ANALYSIS; REACTION TIME; SYNTHESIS;

EID: 33644589071     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v05-115     Document Type: Article

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