Facile synthesis of trifluoromethyl-substituted enynes: Remarkable reactivity and stereoselectivity of tributyl(3,3,3-trifluoropropynyl)stannane in carbostannylation of alkynes

Chemistry Letters

Volumn 34, Issue 12, 2005, Pages 1700-1701

  Shimizu, Masaki ^a   Jiang, Guofang ^a   Murai, Masahito ^a   Takeda, Youhei ^a   Nakao, Yoshiaki ^a   Hiyama, Tamejiro ^a   Shirakawa, Eiji ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33644558732     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.1700     Document Type: Article

References (48)

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43. 3 complex.
44. Reaction of alkyl acetylenes with 1 failed to give the carbostannylation products under the conditions.
45. See Supporting Information.
46. In marked contrast, no reaction took place with tributylpropynylstannane under the same conditions, suggesting that the fluorine atoms played a crucial role in the reaction of 1.
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