A new twist in anion binding: Metallo-helicate hosts for anionic guests

Dalton Transactions

Volumn 6, Issue 10, 2006, Pages 1277-1284

  Goetz, Sandrine ^a   Kruger, Paul E ^a  

^a TRINITY COLLEGE DUBLIN   (Ireland)

Author keywords

[No Author keywords available]

Indexed keywords

CONDENSATION; HYDROGEN; INFRARED SPECTROSCOPY; IRON COMPOUNDS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; SALTS; STOICHIOMETRY;

INTRAHELICAL CAVITY; LIGANDS; RIGID AROMATIC DIAMINES;

AROMATIC COMPOUNDS;

EID: 33644540496     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b514580e     Document Type: Article

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59. - ions clearly suppresses these phenomena. See also ref. 21.
60. 2O) is contained within the intrahelical cavity and interacts with the host through hydrogen bonding.
61. - ion with the amide.
62. - and we would anticipate them to successfully displace it from the cavity if it were there.
63. -). To the best of our knowledge this observation is without precedent in the literature and will be the subject of further investigation.