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Volumn 78, Issue 2, 2006, Pages 341-349

Development of palladium catalysts for asymmetric hydroamination reactions

Author keywords

Alkenes; Amines; Asymmetric catalysis; Hydroamination; Palladium

Indexed keywords


EID: 33644517199     PISSN: 00334545     EISSN: None     Source Type: Journal    
DOI: 10.1351/pac200678020341     Document Type: Conference Paper
Times cited : (69)

References (31)
  • 4
    • 19944423511 scopus 로고    scopus 로고
    • M. Beller and C. Bolm (Eds.), VCH, Weinheim
    • nd ed., M. Beller and C. Bolm (Eds.), 2, pp. 403-414, VCH, Weinheim (2004);
    • (2004) nd Ed. , vol.2 , pp. 403-414
    • Beller, M.1    Tillack, A.2    Seayad, J.3
  • 8
    • 20344373823 scopus 로고    scopus 로고
    • B. Cornils and W. A. Herrmann (Eds.), VCH, Weinheim
    • nd ed., B. Cornils and W. A. Herrmann (Eds.), 1, pp. 513-524, VCH, Weinheim (2001);
    • (2001) nd Ed. , vol.1 , pp. 513-524
    • Taube, R.1
  • 15
    • 17944371189 scopus 로고    scopus 로고
    • and refs. therein
    • "Blank" reactions are always monitored in our work, where the substrates are subjected to the same reaction conditions in the absence of catalyst. The uncatalyzed addition of amines to activated alkene substrates may proceed in polar media and/or in the presence of Brønsted acids. For example, see: A. D. Zotto, W. Baratta, A. Fulluga, P. Rigo. Inorg. Chim. Acta 358, 2749 (2005) and refs. therein.
    • (2005) Inorg. Chim. Acta , vol.358 , pp. 2749
    • Zotto, A.D.1    Baratta, W.2    Fulluga, A.3    Rigo, P.4
  • 27
    • 33644514117 scopus 로고    scopus 로고
    • note
    • The yield of the product was somewhat lower with the catalyst generated in situ, which we attributed to the limited solubility of the precursor in toluene.


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