Experimental investigation and calculation of methane hydrate formation conditions in the presence of ethylene glycol and sodium chloride

Journal of Chemical and Engineering Data

Volumn 49, Issue 4, 2004, Pages 847-851

  Eichholz, C ^b   Majumdar, A ^a   Clarke, M A ^a   Oellrich, L R ^b   Bishnoi, P R ^a  

^a UNIVERSITY OF CALGARY   (Canada)

^b UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CALIBRATION; CARBON DIOXIDE; CRYSTAL STRUCTURE; GAS HYDRATES; GLYCOLS; GREENHOUSE EFFECT; MIXTURES; SODIUM CHLORIDE; SOLUTIONS; THERMOCOUPLES;

ETHYLENE GLYCOLS; INCIPIENT SOLIDS; MARINE FLOORS; METHANE HYDRATE;

METHANE;

EID: 3342941857     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je034179f     Document Type: Article

References (21)

1. Sloan, E. D. Clathrate Hydrates of Natural Gases; Marcel Dekker: New York, 1998.
2. Englezos, P. Clathrate Hydrates. Ind. Eng. Chem. Res. 1993, 32, 1251-1274.
3. Robinson D. B.; Ng, H.-J. Hydrate Formation and Inhibition in Gas or Gas Condensate Streams. J. Can. Petrol. Technol. 1986, 25 (4), 26-30.
4. Ng, H.-J.; Chen, C.; Robinson, D. B. The Effect of Ethylene Glycol or Methanol on Hydrate Formation in Systems Containing Ethane, Propane, Carbon Dioxide, Hydrogen Sulfide or a Typical Gas Condensate. Gas Processors Association Research Report RR-92, September, 1985.
5. Song, K. Y.; Kobayashi, R. Final Hydrate Stability Conditions of a Methane and Propane Mixture in the Presence Pure Water and Aqueous Solutions of Methanol and Ethylene Glycol. Fluid Phase Equilib. 1989, 47, 295-308.
6. Dholabhai, P. D.; Parent, J. S.; Bishnoi, P. R. Equilibrium Conditions for Hydrate Formation from Binary Mixtures of Methane and Carbon Dioxide in the Presence of Electrolytes, Methanol and Ethylene Glycol. Fluid Phase Equilib. 1997, 141, 235-246.
7. Bishnoi, P. R.; Dholabhai, P. D.; Mahadev, K. N. Hydrate Phase Equilibria in Inhibited and Brine Systems, A Joint Research Report by the Gas Processors Association and the Gas Research Institute. Research Report RR-156, August, 1996.
8. Bishnoi, P. R.; Dholabhai, P. D.; Mahadev, K. N. Solid Deposition in Hydrocarbon Systems - Gas Hydrate Equilibrium Studies. Gas Research Institute, Technical Report, GRI-96/0144. Chicago, IL, April, 1996.
9. Yousif, M. H. Effect of Under-Inhibition with Methanol and Ethylene Glycol on the Hydrate Control Process. Annual Proceedings, Offshore Technology Conference, Houston, TX Part 4 (of 4), May 6-9, 1996.
10. Mahmoodaghdam, E.; Bishnoi, P. R. Equilibrium Data for Methane, Ethane and Propane Incipient Hydrate Formation in Aqueous Solutions of Ethylene Glycol and Diethylene Glycol. J. Chem. Eng. Data 2002, 47, 278-281.
11. Majumdar, A.; Mahmoodaghdam, E.; Bishnoi, P. R. Equilibrium Hydrate Formation Conditions for Hydrogen Sulfide, Carbon Dioxide and Ethane in Aqueous Solutions of Ethylene Glycol and Sodium Chloride. J. Chem. Eng. Data 2000, 45, 20-22.
12. Clarke, M. A.; Bishnoi, P. R. Prediction of Hydrate Formation Conditions in Aqueous Electrolyte Solutions in the Presence of Methanol. Proceedings of the Fourth International Conference on Gas Hydrates. Yokohama, Japan, May 17-20, 2002, 406.
13. Clarke, M. A.; Bishnoi, P. R. Development of a New Equation of State for Mixed Salt and Mixed Solvent Systems, and Application to Vapour Liquid and Solid (Hydrate) Vapour Liquid Equilibrium Calculations. Fluid Phase Equilib., accepted.
14. Mahadev, K. N.; Bishnoi, P. R. Equilibrium Conditions for the Hydrogen Sulphide Hydrate Formation in the Presence of Electrolytes and Methanol. Can. J. Chem. Eng. 1999, 77, 718-722.
15. Parent, J. S. Investigations into the Nucleation Behavior of the Clathrate Hydrates of Natural Gas Component, M.Sc. Thesis, University of Calgary, 1993.
16. Parent, J. S. A variable volume Sapphire cell. In-house report submitted to P. R. Bishnoi, University of Calgary, 1993.
17. Dholabhai, P. D.; Englezos, P.; Kalogerakis, N.; Bishnoi, P. R. Equilibrium Conditions for Methane Hydrate Formation in Aqueous Mixed Electrolyte Solutions. Can. J. Chem. Eng. 1991, 69, 800-805.
18. Rock, A. Experimentelle und theoretische Untersuchung zur Hydratbildung aus Gasgemischen in inhibitorhaltigen wässrigen Lösungen. Dissertation, Universität Karlsruhe, 2002.
19. Trebble, M. A.; Bishnoi, P. R. Development of a New FourParameter Cubic Equation of State. Fluid Phase Equilib. 1987, 35, 1-18.
20. Trebble, M. A.; Bishnoi, P. R. Extension of the Trebble-Bishnoi Equation of State to Mixtures. Fluid Phase Equilibria 1988, 40, 1-21.
21. van der Waals, J. H.; Platteeuw, J. C. Clathrate Solutions. Adv. Chem. Phys. 1959, 2, 1-57.