Photooxidation of Co-thiolato complexes in protic and aprotic solvents

Chemical Communications

Volumn , Issue 9, 2006, Pages 997-999

  Hernandez, Billy ^a   Wang, Yanju ^a   Zhang, Dong ^a   Selke, Matthias ^a  

^a CALIFORNIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX; SINGLET OXYGEN; SOLVENT; THIOL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; HYDROGEN BOND; PHOTOOXIDATION; REACTION ANALYSIS;

EID: 33244481031     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b514601a     Document Type: Article

References (12)

1. C. A. Grapperhaus and M. Y. Darensbourg, Acc. Chem. Res., 1998, 31, 451 and references therein.
2. J. A. Kovacs, Chem. Rev., 2004, 104, 825 and references therein.
3. T. C. Harrop and P. K. Mascharak, Acc. Chem. Res., 2004, 37, 253 and references therein.
4. C. Galvez, D. G. Ho, A. Azod and M. Selke, J. Am. Chem. Soc., 2001, 123, 3381.
5. Complexes 1 and 2 were prepared by literature methods. R. H. Lane, F. A. Sedor, M. J. Gilroy, P. F. Eisenhardt, J. P. Bennett, R. X. Ewall and L. E. Bennett, Inorg. Chem., 1977, 16, 93;
6. M. H. Dickman, R. J. Doedens and E. Deutsch, Inorg. Chem., 1980, 19, 945. Complex 5 was purchased from Sigma-Aldrich.
7. R. Higgins, C. S. Foote and H. Cheng, Adv. Chem. Ser., 1968, 77, 102.
8. F. Jensen, A. Greer and E. L. Clennan, J. Am. Chem. Soc., 1998, 120, 4439;
9. C.-L. Gu, C. S. Foote and M. L. Kacher, J. Am. Chem. Soc., 1981, 103, 5949.
10. t, presumably because of a decrease of the nucleophilicity at the sulfur atom. S. M. Bonesi, M. Fagnoni and A. Albini, J. Org. Chem., 2004, 69, 928.
11. J. N. Smith, J. T. Hoffman, Z. Shirin and C. J. Carrano, Inorg. Chem., 2005, 44, 2012;
12. J. N. Smith, Z. Shirin and C. J. Carrano, J. Am. Chem. Soc., 2003, 125, 868.