(O-benzoylsalicylato)copper(II) complexes as synthetic enzyme-product models for flavonol 2,4-dioxygenase

Inorganic Chemistry Communications

Volumn 9, Issue 3, 2006, Pages 251-254

  Kaizer, József ^a   Góger, Szabina ^b   Speier, Gábor ^a,b   Réglier, Marius ^c   Giorgi, Michel ^c  

^a INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

^b UNIVERSITY OF PANNONIA   (Hungary)

^c AIX MARSEILLE UNIVERSITY   (France)

Author keywords

Carboxylates; Copper; Dioxygenation; Flavonol; O Benzoylsalicylic acid

Indexed keywords

EID: 33144485036     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2005.11.011     Document Type: Article

References (26)

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23. 8ClCu: C, 57.15; H, 4.07; N, 6.06%. Found: C, 56.86; H, 4.01; N, 6.12%.
24. 8ClCu: C, 58.25; H, 4.47; N, 5.82%. Found: C, 58.46; H, 4.51; N, 5.75%.
25. -3. The computer program used were SHELXL97 [20]. The structure was solved by direct and difmap methods (SIR92) [21]. CCDC reference number: 288963.
26. 3 of the reaction mixture at r.t. and the conversion of flavonol into O-benzoylsalicylic acid was determined by GC as the methylated derivative in the presence of benzoin (internal standard).