Modelling of natural and synthetic polyelectrolyte interactions in natural waters by using SIT, Pitzer and Ion Pairing approaches

Marine Chemistry

Volumn 99, Issue 1-4, 2006, Pages 93-105

  Crea, Francesco ^a   Giacalone, Alba ^b   Gianguzza, Antonio ^b   Piazzese, Daniela ^b   Sammartano, Silvio ^a  

^a UNIVERSITY OF MESSINA   (Italy)

^b UNIVERSITY OF PALERMO   (Italy)

Author keywords

Alginic and fulvic acids; Artificial seawater; Dependence on medium and ionic strength; Ion Pair models; Natural and synthetic polyelectrolytes; Pitzer; Specific ion Interaction Theory (SIT)

Indexed keywords

ELECTROLYTE; SEAWATER;

EID: 32844463449     PISSN: 03044203     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.marchem.2005.03.012     Document Type: Conference Paper

References (46)

1. G. Biedermann Ionic media Dahlem Workshop on the Nature of Seawater 1975 Dahlem Konferenzen Berlin 339 362
2. G. Biedermann Introduction to the specific interaction theory with emphasis on chemical equilibria E.A. Jenne E. Rizzarelli V. Romano S. Sammartano Metal Complexes in Solution 1986 Piccin Padua, Italy 303 314
3. C. Bretti, C. Foti, and S. Sammartano A new approach in the use of SIT in determining the dependence on ionic strength of activity coefficients. Application to some chloride salts of interest in the speciation of natural fluids Chem. Speciat. Bioavailab. 16 3 2004 105 110
4. L. Ciavatta The specific interaction theory in evaluating ionic equilibria Ann. Chim. 70 1980 551 567
5. L. Ciavatta The specific interaction theory in equilibrium analysis. Some empirical rules for estimating interaction coefficients of metal ion complexes Ann. Chim. (Rome) 80 1990 255 263
6. F. Crea, A. De Robertis, C. De Stefano, S. Sammartano, A. Gianguzza, and D. Piazzese Binding of acrylic and sulphonic polyanions by open-chain polyammonium cations Talanta 53 2001 1241 1248
7. F. Crea, P. Crea, C. De Stefano, O. Giuffrè, A. Pettignano, and S. Sammartano Thermodynamic parameters for the protonation of poly(allilamine) in concentrated LiCl(aq) and NaCl(aq) J. Chem. Eng. Data 49 2004 658 663
8. (aq) at 25°C J. Solution Chem. 33 5 2004 499 528
9. 2+ complexes of low molecular weight ligands in aqueous solution J. Chem. Soc. Dalton Trans. 1985 2353 2361
10. C. De Stefano, P. Princi, C. Rigano, and S. Sammartano Computer analysis of equilibrium data in solution. ESAB2M: an improved version of the ESAB program Ann. Chim. (Rome) 77 1987 643 675
11. C. De Stefano, C. Foti, A. Gianguzza, C. Rigano, and S. Sammartano The equilibrium studies in natural fluids. The use of synthetic sea waters and other media as background salts Ann. Chim. (Rome) 84 1994 159 175
12. C. De Stefano, P. Mineo, C. Rigano, and S. Sammartano Computer tools for the speciation of natural fluids A. Gianguzza E. Pelizzetti S. Sammartano Marine Chemistry-An Environmental Analytical Chemistry Approach 1997 Kluwer Amsterdam 71 83
13. C. De Stefano, C. Foti, A. Gianguzza, and S. Sammartano The single salt approximation for the major components of seawater: association and acid-base properties Chem. Speciat. Bioavailab. 10 1 1998 27 29
14. C. De Stefano, A. Gianguzza, D. Piazzese, and S. Sammartano Polyacrylate protonation in various aqueous media at different temperatures and ionic strengths J. Chem. Eng. Data 45 5 2000 876 881
15. C. De Stefano, C. Foti, A. Gianguzza, and S. Sammartano The interaction of amino acids with the major constituents of natural waters at different ionic strengths Mar. Chem. 72 2000 61 76
16. C. De Stefano, A. Gianguzza, D. Piazzese, and S. Sammartano Speciation of polyelectrolytes in natural fluids. Protonation and interaction of polymetacrylates with major components of seawater Talanta 58 2 2002 405 417
17. C. De Stefano, A. Gianguzza, D. Piazzese, and S. Sammartano Polyacrylates in aqueous solution. The dependence of protonation on molecular weight, ionic medium and ionic strength React. Funct. Polym. 55 2003 9 20
18. (aq) J. Solution Chem. 32 11 2003 967 976
19. C. De Stefano, A. Gianguzza, D. Piazzese, and S. Sammartano Speciation of organic matter in natural waters-interaction of polyacrylates and polymethacrylates with major cation components of seawater Mar. Chem. 86 2004 33 44
20. C. De Stefano, A. Gianguzza, D. Piazzese, and S. Sammartano Modelling of proton and metal exchange in the alginate biopolymer Anal. and Bioanal. Chem. 383 4 2005 587 596
21. R.M. Garrels, and M.E. Thompson A chemical model for sea water at 25°C and one atmosphere total pressure Am. J. Sci. 260 1962 57 66
22. I. Grenthe I. Puigdomenech Modelling in Aquatic Chemistry 1997 OECD, Nuclear Energy Agency Paris
23. E.A. Guggenheim Application of Statistical Mechanics 1966 Claredon Press Oxford
24. E. Högfeldt, T. Miyajima, J.A. Marinsky, and M. Muhammed Application of a simple three parameter mode to titration data for some polyelectrolytes Acta Chem. Scand. 43 1989 496 499
25. A. Katchalsky Problems in the physical chemistry of polyelectrolytes J. Polym. Sci. 12 1954 159
26. A. Katchalsky, and P. Spitnik Potentiometric titrations of polymethacrylic acid J. Polym. Sci. 2 1947 432
27. Martell, A.E., Smith, R.M. 1997. Stability Constants of Metal Complexes. NIST PC-Based Database: National Institute of Standards and Technology: Gaithersburg, M D.
28. P.M. May, and K. Murray Database of chemical reactions designed to achieve thermodynamic consistency automatically J. Chem. Eng. Data 46 2001 1035 1040
29. F.J. Millero Seawater as a multicomponent electrolyte solution E.D. Goldberg The Sea Ideas and Observations on Progress in the Study of the Seas vol. 5 1974 Wiley New York
30. F.J. Millero Thermodynamics of the carbon dioxide systems in the oceans Geochim. Cosmochim. Acta 59 4 1995 661 677
31. F.J. Millero The carbonate system in marine environments A. Gianguzza E. Pelizzetti S. Sammartano Chemical processes in Marine Environments 2000 Springer Berlin 9 42 chapter 1
32. F.J. Millero Sea water as an electrolyte A. Gianguzza E. Pelizzetti S. Sammartano Chemistry of Marine Water and Sediments 2002 Springer-Verlag Berlin 3 32 chap. 1
33. F.J. Millero, and W.H. Leung The thermodynamics of sea water at one atmosphere Am. J. Sci. 276 1976 1035 1077
34. Pettit, L.D. Powell, K.J. 1993. IUPAC Stability Constants Database; Academic Software: Outlay, U. K.
35. K.S. Pitzer Thermodynamics of electrolytes: I. Theoretical basis and general equations J. Phys. Chem. 77 2 1973 268 277
36. K.S. Pitzer Activity Coefficients in Electrolyte Solutions 2a ed. 1991 CRC Press Boca Raton, FL
37. K.S. Pitzer, and G. Mayorga Thermodynamics of electrolytes: II. Activity and osmotic coefficients for strong electrolytes with one or both ions univalent J. Phys. Chem. 77 19 1973 2300 2308
38. C. Rey-Castro, R. Herrero, and M.E. Sastre de Vicente Gibbs-Donnan and specific ion interaction theory description of the effect of ionic strength on proton dissociation of alginic acid J. Electroanal. Chem. 564 2004 223 230
39. R.A. Robinson The vapour pressure and osmotic equivalence of sea water J. Mar. Biol. Assoc. UK 33 1954 49
40. L.G. Sillen The physical chemistry of sea water M. Sears Oceanography 1961 Amer. Assoc. Adv. Sci. Washington 549 582
41. L.G. Sillén, and A.E. Martell Stability constants of metal-ion complexes Spec. Pub. The Chemical Society vol. 17 1964 Wiley London
42. L.G. Sillén, and A.E. Martell Stability constants of metal ion complexes. Supplement Special Pub. vol. 25 1971 The Chemical Society London
43. E. Tipping Humic ion-binding model VI: an improved description of the interactions of protons and metal ions with humic substances Aquat. Geochem. 4 1998 3 48
44. E. Tipping Cation Binding by Humic Substances 2002 Cambrige University Press Cambrige
45. E. Tipping, C.A. Backes, and M.A. Hurley The complexation of protons, aluminium and calcium by aquatic humic substances: a model incorporating binding-site heterogeneity and macroionic effects Water Res. 22 1988 597 611
46. M. Whitfield Sea water as an electrolyte solution J.P. Riley G. Skirrow 2nd ed. Chemical Oceanography vol. 1 1975 Academic Press London 43 171