Adaptive dendron: A bile acid oligomer behaving as both normal and inverse micellar mimic

Organic Letters

Volumn 8, Issue 3, 2006, Pages 399-402

  Ghosh, Sanjib ^a   Maitra, Uday ^a,b  

^a INDIAN INSTITUTE OF SCIENCE   (India)

^b JAWAHARLAL NEHRU CENTRE FOR ADVANCED SCIENTIFIC RESEARCH   (India)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 32644447578     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol052631+     Document Type: Article

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39. 3).
40. 3).
41. Dendrons 1 and 2 were not soluble in hexane.
42. Sodium salts of dendrons 1 and 2 were not soluble in pure water.
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44. 2O (1:1) system at low concentrations
45. This dye solubilization was not due to an acid-base type of interaction because 1, having a similar functional group, did not show dye extraction. Possibly the tripodal geometry of 2 assisted dye encapsulation better with additional functional groups. Compound 1, on the other hand, has a tweezerlike geometry with fewer polar groups inside the cleft.
46. This observation is very similar to what was observed in the case of Orange OT extraction (Figure 2A). In a nonpolar solvent, a small portion of methyl deoxycholate possibly aggregates to form an inverse micelle type of structure.
47. 1H NMR spectra of 1 and 2 did not change with change in concentration, suggesting that self-aggregation was negligible.
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