Kinetics of the recovery of active anthraquinones

Industrial and Engineering Chemistry Research

Volumn 45, Issue 3, 2006, Pages 986-992

  Sandelin, Fredrik ^a,d   Oinas, Pekka ^b,e   Salmi, Tapio ^a,d   Paloniemi, Juhani ^e   Haario, Heikki ^c,f  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

^b KEMIRA OYJ   (Finland)

^c ProfMath   (Finland)

^d Neste Oil Oyj   (Finland)

^e KemFine Oy   (Finland)

^f LAPPEENRANTA UNIVERSITY OF TECHNOLOGY   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM COMPOUNDS; CHEMICAL REACTORS; HYDROGEN PEROXIDE; HYDROGENATION; OXIDATION; REACTION KINETICS; REGRESSION ANALYSIS; SODIUM;

CONVERSION KINETICS; EPOXIDED ALKYLTETRAHYDROANTHRAQUINONE (EPOXIDE); ISOTHERMAL SLURRY REACTORS; KINETIC MODELS;

KETONES;

ALUMINUM COMPOUNDS; CHEMICAL REACTORS; HYDROGEN PEROXIDE; HYDROGENATION; KETONES; OXIDATION; REACTION KINETICS; REGRESSION ANALYSIS; SODIUM;

EID: 32644436913     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie050593s     Document Type: Article

References (17)

1. Powell, R. Hydrogen Peroxide; Noyés Development Co.: New York, 1968.
2. Kirk, T.; Othmer, K. Encyclopedia of Chemical Technology; Wiley: New York, 1981; Vol. 13.
3. Ullman's Encyclopedia of Industrial Chemistry, 5th ed.; VCH Verlagsgesellshaft: Weinheim, 1989; Vol. A13, pp 447-464.
4. Berglin, T.; Schöön, N.-H. Kinetic and Mass Transfer Aspects of the Hydrogénation Stage of the Anthraquinone Process for Hydrogen Peroxide Production. Ind. Eng. Chem. Process Des. Dev. 1981, 20, 615-621.
5. Berglin, T.; Schöön, N.-H. Selectivity Aspects of the Hydrogenation Stage of the Anthraquinone Process for Hydrogen Peroxide Production. Ind. Eng. Chem. Process Des. Dev. 1983, 22, 150-153.
6. 2 catalyst in the liquid phase. J. Mol. Catal. 1992, 75, 321-332.
7. 2. J. Mol Catal. A 1995, 101, 61-74.
8. Santacesaria, E.; Ferro, R.; Ricci, S.; Carrà, S. Kinetic Aspects in the Oxidation of Hydrogenated 2-Ethyltetrahydroanthraquinone. Ind. Eng. Chem. Res. 1987, 26, 155-159.
9. Santacesaria, E.; Wilkinson, P.; Babini, P.; Carrà S. Hydrogenation of 2-Ethyltetrahydroanthraquinone in the Presence of Palladium Catalyst. Ind. Eng. Chem. Res. 1988, 27, 780-784.
10. Santacesaria, E.; Di Serio, M.; Velotti, R.; Leone, U. Kinetics, MassTransfer, and Palladium Catalyst Deactivation in the Hydrogenation Step of the Hydrogen Peroxide Synthesis via Anthraquinone. Ind. Eng. Chem. Res. 1994, 33, 277-284.
11. Santacesaria, E.; Di Serio, M.; Velotti, R.; Leone, U. Hydrogenation of the aromatic rings of 2-ethylanthraquinone on palladium catalyst. J. Mol. Catal. 1994, 94, 37-46.
12. Santacesaria, E.; Di Serio, M.; Iengo, P. Examples of hydrogenation in semibatch and continuous slurry reactors. Catal. Today 1999, 52, 363376.
13. Santacesaria, E.; Di Serio, M.; Russo, A.; Leone, U.; Velotti, R. Kinetic and catalytic aspects in the hydrogen peroxide production via anthraquinone, Chem. Eng. Sci. 1999b, 54, 2799-2806.
14. Sandelin, F.; Oinas, P.; Salmi, T.; Haario, H. Kinetics of the Catalyst Deactivation in the Recovery of Active Antharquinones. Studies Surf. Sci. Catal. 1994, 88, 635-640.
15. Haario, H. Modest User Manual; ProfMath, Ltd.: Helsinki, 1994.
16. Hindmarsh, A. C. ODEPACK-A Systematized Collection of ODE-Solvers. In Scientific Computing; Stepleman, R., et al., Eds.; IMACS/North-Holland Publishing Co.: New York, 1983; pp 55-64.
17. Henrici, P. Discrete Variable Methods in Ordinary Differential Equations; Wiley: New York, 1962.