[3+2] Cross-coupling reactions of aziridines with isocyanates catalyzed by nickel(II) iodide

Organic Letters

Volumn 8, Issue 3, 2006, Pages 379-382

  Munegumi, Takeshi ^a   Azumaya, Isao ^b   Kato, Takako ^b   Masu, Hyuma ^b   Saito, Shinichi ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

^b TOKUSHIMA BUNRI UNIVERSITY   (Japan)

Author keywords

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Indexed keywords

EID: 32644436280     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol052417l     Document Type: Article

References (20)

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14. Although the reaction proceeded when we carried out the reaction at lower temperature (50 °C or 80 °C), a longer reaction time was required.
15. 4 was also very low.
16. 2 = 0.712; R1 = 0.0394, wR2 = 0.0825 ([I > 2σ(I)], R1 = 0.0876, and wR2 = 0.0895 (all data). CCDC-280438.
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20. Alternatively, the iodide may react as a nucleophile in this process. The stereochemical study of this reaction will distinguish the processes.