Thermodynamics and kinetics of reactions between C1-C3 hydrocarbons and calcium sulfate in deep carbonate reservoirs

Geochemical Journal

Volumn 40, Issue 1, 2006, Pages 87-94

  Yue, Changtao ^a   Li, Shuyuan ^a   Ding, Kangle ^a   Zhong, Ningning ^a  

^a CHINA UNIVERSITY OF PETROLEUM   (China)

Author keywords

C1 C3 hydrocarbons; Kinetics and thermodynamics; Solid calcium sulfate; Thermal simulation experiments; TSR

Indexed keywords

HYDROCARBON RESERVOIR; ORGANIC GEOCHEMISTRY; REACTION KINETICS; THERMODYNAMICS;

EID: 32444444720     PISSN: 00167002     EISSN: None     Source Type: Journal    
DOI: 10.2343/geochemj.40.87     Document Type: Article

References (35)

1. Alonso-Azcarate J., Bottrell, S. H. and Tritlla, J. (2001) Sulfur redox reactions and formation of native sulfur veins during low grade metamorphism of gypsum evaporates, Cameros Basin (NE Spain). Chemical Geology 174, 389-402.
2. Anisimov, L. A. (1978) Conditions of abiogenic reduction of sulfate in oil- and gas-bearing basins. Geochemistry International 15, 63-71.
3. Bildstein, O., Worden, R. H. and Brosse, E. (2001) Assessment of anhydrite dissolution as the rate-limiting step during thermochemical sulfate reduction. Chemical Geology 176, 173-189.
4. Burnham, A. K. and Sweeney, J. J. (1989) A chemical kinetic model of vitrinite maturation and reflectance. Geochimica et Cosmochimica Acta 53, 2649-2657.
5. Cai, Chunfang, Worden, R. H., Bottrell, S. H. et al. (2003) Thermochemical sulphate reduction and the generation of hydrogen sulphide and thiols (mercaptans) in Triassic carbonate reservoirs from the Sichuan Basin, China. Chemical Geology 202, 39-57.
6. Ceng, K. M., Wang, T. G. and Zhong, N. N. (1996) Geochemistry of Source Rock. Science Press, Beijing, 203-233 (in Chinese).
7. Claypool, G. E. and Mancini, E. A. (1989) Geochemical relationships of petroleum in Mesozoic reservoirs to carbonate source rocks of Jurassic Smackover Formation, southwestern Alabama. American Association Petroleum Geology Bulletin 73, 904-924.
8. Dean, J. A. (1991) Lange's Handbook of Chemistry. Science Press, Beijing, 9-67 (in Chinese).
9. 2S. Geochemical Transformations of Sedimentary Sulfur (Vairavamurthy, M. A. and Schoonen, M. A. A. eds.), ACS Symposium Series 612, 412-425.
10. Gorshkov, M. V., Gorshkov, V. I. and Ivlen, A. A. (2001) Modelling of natural thermochemical sulphate reduction process (abstract). Abstract for 20th International Meeting on Organic Geochemistry, Nancy, France.
11. Helgeson, H. C., Owens, C. E., Knox, A. M. et al. (1998) Calculation of the standard model thermodynamic properties of crystalline, liquid, and gas organic molecules at high temperatures and pressures. Geochimica et Cosmochimica Acta 62, 985-1081.
12. Hill, C. A. (1990) Sulfuric acid speleogenesis of Carlsbad cavern and its relationship to hydrocarbons, Delaware Basin, New Mexico and Texas. AAPG Bulletin 74, 1685-1694.
13. Huang, W. L. (1996) Experimental study of vitrinite maturation: effects of temperature, time, pressure, water and hydrogen index. Organic Geochemistry 24, 233-241.
14. 2, in Paleozoic reservoirs of western Canada. Geochemical Transformations of Sedimentary Sulfur (Vairavamurthy, M. A. and Schoonen, M. A. A. eds.), ACS Symposium Series 612, 426-438.
15. Kiranas, E. R., Tzouwara-karayanni, S. M. and Karayannis, M. I. (1997) The reaction of glutamic acid and trinitrobenzenesulfonic acid-kinetic study and analytical application. Talanta 44, 1113-1121.
16. Kiyosu, Y. (1980) Chemical reduction and sulfur isotope effects of sulfate by organic matter under hydrothermal conditions. Chemical Geology 30, 47-56.
17. Kiyosu, Y. and Krouse, H. R. (1990) The role of organic acid in the abiogenic reduction of sulfate and the sulfur isotope effect. Journal of Geochemistry 24, 21-27.
18. Krouse, H. R., Viau, C. A. and Eliuk, L. S. (1988) Chemical and isotopic evidence of thermo chemical sulfate reduction by light hydrocarbon gases in deep carbonate reservoirs. Nature 333, 415-419.
19. Leventhal, J. S. (1990) Organic matter and thermochemical sulfate reduction in the Viburnum Trend, Southeast Missouri. Economic Geology 85, 622-632.
20. Li, S. Y. (2000) The Application of Chemical Kinetics to Estimate Hydrocarbon Evolution in the Basin. Petroleum University Press, Dongying, 89-90 (in Chinese).
21. Machel, H. G. (1987) Saddle dolomite as a by-product of chemical compaction and thermochemical sulfate reduction. Geology 15, 936-940.
22. Machel, H. G. (1998) Gas souring by thermochemical sulfate reduction at 140°C: discussion. American Association Petroleum Geology Bulletin 82, 1870-1873.
23. Machel, H. G. (2001) Bacterial and thermochemical sulfate reduction in diagenetic settings - old and new insights. Sedimentary Geology 40, 143-175.
24. Machel, H. G., Krouse, H. R. and Sassen, R. (1995) Products and distinguishing criteria of bacterial and thermochemical sulfate reduction. Applied Geochemistry 10, 373-389.
25. Manzano, B. K., Fowler, M. G. and Machel, H. G. (1997) The influence of thermochemical sulfate reduction on hydrocarbon composition in Nisku reservoir, Brazeau River area, Alberta, Canada. Organic Geochemistry 27, 507-521.
26. 4 matrix. Journal of Physics and Chemistry of Solids 62, 521-530.
27. Sassen, R. and Moore, C. H. (1988) Framework of hydrocarbon generation and destruction in eastern Smackover trend. American Association Petroleum Geology Bulletin 72, 649-663.
28. Schenk, H. J. and Dieckmann, V. (2004) Prediction of petroleum formation: the influence of laboratory heating rates on kinetic parameters and geological extrapolations. Marine and Petroleum Geology 21, 79-95.
29. Snowdon, L. R. (2001) Natural gas composition in a geological environment and the implications for the processes of generation and preservation. Organic Geochemistry 32, 913-931.
30. Svetozar, M., Durdica, D., Miroslava, M. et al. (2002) Influence of chemical synthesis on the crystallization and properties of zinc oxide. Materials Chemistry and Physics 77, 521-530.
31. Toland, W. G. (1960) Oxidation of organic compounds with aqueous sulfate. Journal of American Chemical Society 82, 1911-1916.
32. Tridinger, P. A., Chambers, L. A. and Smith, J. W. (1985) Low temperature sulfate reduction: biological versus abiological. Canadian Journal of Earth Science 22, 1910-1918.
33. Wang, X. H., Du, Y. M. and Liu H. (2004) Preparation, characterization and antimicrobial activity of chitosan-Zn complex. Carbohydrate Polymers 56, 21-26.
34. Wen, L., Liang, W. X., Zhang, Z. G. et al. (1989) The Infrared Spectroscopy of Minerals. Chongqing University Press, Chongqing, 55-65 (in Chinese).
35. 2S-producing reactions in deep carbonate gas reservoirs: Khuff Formation, Abu Dhabi. Chemical Geology 133, 157-171.