7-Chloro-7-cyanobicycIo[4.2.0]octan-8-one (Prepared from Chlorocyanoketene)

Synthetic Communications

Volumn 19, Issue 19, 1989, Pages 3283-3287

  Fishbein, Paul L ^a   Moore, Harold W ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 3242815668     PISSN: 00397911     EISSN: 15322432     Source Type: Journal    
DOI: 10.1080/00397918908052730     Document Type: Article

References (5)

1. Fishbein, P. L.; Moore, H. W. J. Org. Chem. 1984, 49, 2190.
2. Biffin, M. C.; Miller, J.; Paul, D. B. “Introduction of the Azido Group” in The Chemistry of the Azido Group, Patai, S., Ed., J. Wiley and Sons Inc., New York, p.,61,1971.
3. Generation of the ketene from 3b was not completely obvious since the possibility of H-atom abstraction from the isopropyl group by a nitrene intermediate was also considered to be a possibility.
4. The procedure for making the pseudoester was from Y. Hachihama, T. Shono J. Chem. Soc. Japan Ind. Chem. Sec. 1955,58, 692 (Chem. Abstr. 50:12015e).
5. Ward, R. S.; “The Preparation of Ketenes” in The Chemistry of Ketenes, Allenes and Related Compounds, Patai, S.; Ed., J. Wiley and Sons, New York, pp., 223–227, 1980.