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Volumn 33, Issue 5, 2004, Pages 626-627

Novel synthesis and bridgehead functionalization of permethylbicyclo[2.2.2] octasilane

Author keywords

[No Author keywords available]

Indexed keywords

LITHIUM DERIVATIVE; PERMETHYLBICYCLO[2.2.2]OCTASILANE; POTASSIUM DERIVATIVE; SILANE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 3242790160     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2004.626     Document Type: Article
Times cited : (18)

References (25)
  • 1
    • 0024733839 scopus 로고
    • For recent reviews of polysilanes, see: R. D. Miller and J. Michl, Chem. Rev., 89, 1359 (1989); R. West, in "The Chemistry of Organic Silicon Compounds," ed. by S. Patai and Z. Rappoport, John Wiley & Sons, Chichester (1989), Part 1, Chap. 19, p 1207.
    • (1989) Chem. Rev. , vol.89 , pp. 1359
    • Miller, R.D.1    Michl, J.2
  • 2
    • 0024733839 scopus 로고
    • ed. by S. Patai and Z. Rappoport, John Wiley & Sons, Chichester Chap. 1
    • For recent reviews of polysilanes, see: R. D. Miller and J. Michl, Chem. Rev., 89, 1359 (1989); R. West, in "The Chemistry of Organic Silicon Compounds," ed. by S. Patai and Z. Rappoport, John Wiley & Sons, Chichester (1989), Part 1, Chap. 19, p 1207.
    • (1989) The Chemistry of Organic Silicon Compounds , Issue.1 PART , pp. 1207
    • West, R.1
  • 3
    • 0000833148 scopus 로고    scopus 로고
    • ed. by Z. Rappoport and Y. Apeloig, John Wiley & Sons, Chichester Chap. 22
    • For recent reviews, see: M. Kira and T. Miyazawa, in "The Chemistry of Organic Silicon Compounds," ed. by Z. Rappoport and Y. Apeloig, John Wiley & Sons, Chichester (1998), Vol. 2, Chap. 22, p 1311; M. Kira and B. Ramachandram, in "Handbook of Photochemistry and Photobiology," ed. by H. S. Nalwa, American Scientific Publishers, Stevenson Ranch, California (2003), Vol. 1, Chap. 3, p 83.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2 , pp. 1311
    • Kira, M.1    Miyazawa, T.2
  • 4
    • 3242764836 scopus 로고    scopus 로고
    • ed. by H. S. Nalwa, American Scientific Publishers, Stevenson Ranch, California Chap. 3
    • For recent reviews, see: M. Kira and T. Miyazawa, in "The Chemistry of Organic Silicon Compounds," ed. by Z. Rappoport and Y. Apeloig, John Wiley & Sons, Chichester (1998), Vol. 2, Chap. 22, p 1311; M. Kira and B. Ramachandram, in "Handbook of Photochemistry and Photobiology," ed. by H. S. Nalwa, American Scientific Publishers, Stevenson Ranch, California (2003), Vol. 1, Chap. 3, p 83.
    • (2003) Handbook of Photochemistry and Photobiology , vol.1 , pp. 83
    • Kira, M.1    Ramachandram, B.2
  • 5
    • 0000041984 scopus 로고
    • D. Declercq, F. C. De Schryver, and R. D. Miller, Chem. Phys. Lett., 186, 467 (1991); for photophysical properties of α,ω-diary- loligosilanes, see: T. Karatsu, T. Shibata, A. Nishigaki, A. Kitamura, Y. Hatanaka, Y. Nishimura, S. Sato, and I. Yamazaki, J. Phys. Chem. B, 107, 12184 (2003), and references cited therein.
    • (1991) Chem. Phys. Lett. , vol.186 , pp. 467
    • Declercq, D.1    De Schryver, F.C.2    Miller, R.D.3
  • 7
    • 0037532936 scopus 로고    scopus 로고
    • and references cited therein
    • For other types of oligosilane with rigid frameworks, see: H. Tsuji, M. Terada, A. Toshimitsu, and K. Tamao, J. Am. Chem. Soc., 125, 7486 (2003), and references cited therein.
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 7486
    • Tsuji, H.1    Terada, M.2    Toshimitsu, A.3    Tamao, K.4
  • 13
    • 3242808507 scopus 로고    scopus 로고
    • note
    • 7 (5, 20.5 g, 63.4 mmol), and stirred for 1 day at ambient temperature. The color of solution turned to brown, then filtered and hydrolysis by dilute hydrochloric acid. The organic phase was extracted with ether, and volatile material was removed in vacuo. Kuger-Rohr distillation (200°C, 0.01 mmHg) gave colorless crystals of 1 (2.60mg, 5.98 mmol) in 19% yield.
  • 19
    • 0001654607 scopus 로고
    • G. D. Honer and L. H. Sommer, J. Am. Chem. Soc., 95, 7700 (1973); See also: R. J. P. Corriu, C. Guerin, and J. J. J. Moreau, Top. Stereochem., 15, 43 (1984); P. Bondjank, C. A. Kapfer, and R. F. Cunico, Organometallics, 2, 336 (1983).
    • (1973) J. Am. Chem. Soc. , vol.95 , pp. 7700
    • Honer, G.D.1    Sommer, L.H.2
  • 20
    • 85026814650 scopus 로고
    • G. D. Honer and L. H. Sommer, J. Am. Chem. Soc., 95, 7700 (1973); See also: R. J. P. Corriu, C. Guerin, and J. J. J. Moreau, Top. Stereochem., 15, 43 (1984); P. Bondjank, C. A. Kapfer, and R. F. Cunico, Organometallics, 2, 336 (1983).
    • (1984) Top. Stereochem. , vol.15 , pp. 43
    • Corriu, R.J.P.1    Guerin, C.2    Moreau, J.J.J.3
  • 21
    • 0012144189 scopus 로고
    • G. D. Honer and L. H. Sommer, J. Am. Chem. Soc., 95, 7700 (1973); See also: R. J. P. Corriu, C. Guerin, and J. J. J. Moreau, Top. Stereochem., 15, 43 (1984); P. Bondjank, C. A. Kapfer, and R. F. Cunico, Organometallics, 2, 336 (1983).
    • (1983) Organometallics , vol.2 , pp. 336
    • Bondjank, P.1    Kapfer, C.A.2    Cunico, R.F.3


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