Tetrafluoroborate salts as site-selective promoters for sol-gel synthesis of mesoporous silica

Journal of the American Chemical Society

Volumn 126, Issue 29, 2004, Pages 9013-9016

  Okabe, Akihiro ^a   Fukushima, Takanori ^a   Ariga, Katsuhiko ^a   Niki, Makiko ^a   Aida, Takuzo ^a  

^a JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CALCINATION; CONDENSATION; FLUORIDE MINERALS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC COMPOUNDS; POROUS SILICON; SALTS; SILICA; SYNTHESIS (CHEMICAL); THERMODYNAMIC STABILITY;

PROMOTERS; SOLID STATE; THERMAL CONDENSATION;

SOL-GELS;

AMPHOPHILE; BORIC ACID; FLUORIDE; FLUORINE DERIVATIVE; SILICIC ACID; SILICON DIOXIDE; SODIUM CHLORIDE; TETRAETHOXYORTHOSILICATE; TETRAFLUOROBORATE; TETRAFLUOROBORATE SALT; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; GEL; HYDRODYNAMICS; HYDROLYSIS; MICELLE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; POROSITY; SOL GEL SYNTHESIS; SOLID STATE; SYNTHESIS; THERMAL ANALYSIS;

EID: 3242786358     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0478532     Document Type: Article

References (16)

1. (a) Holmes, R. R. Chem. Rev. 1990, 90, 17-31.
2. (b) Brinker, C. J.; Scherer, G. W. Sol-gel science: the physics and chemistry of sol-gel processing; Academic Press: London, 1990.
3. (a) Corriu, R. J.; Guerin, C.; Henner, B. J. L.; Man, W. C. Organometallics 1988, 7, 237-238.
4. (b) Holmes, R. R.; Deiters, J. A. J. Am. Chem. Soc. 1990, 112, 7197-7202.
5. (a) Schmidt-Winkel, P.; Yang, P.; Margolese, D. I.; Chmelka, B. F.; Stucky, G. D. Adv. Mater. 1999, 11, 303-307.
6. (b) Kim, W. J.; Yoo, J. C.; Hayhurst, D. T. Microporous Mesoporous Mater. 2002, 49, 125-137.
7. (a) Feher, F. J.; Phillips, S. H.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 3397-3398.
8. (b) Farooq, O. J. Chem. Soc., Perkin Trans. 1 1998, 661-665.
9. (a) Marcus, Y. J. Chem. Soc., Faraday Trans. 1991, 87, 2995-2999.
10. (b) Leontidis, E. Curr. Opin. Colloid Interface Sci. 2002, 7, 81-91.
11. See Supporting Information.
12. (a) Tanev, P. T.; Pinnavaia, T. J. Science 1995, 267, 865-867.
13. (b) Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Science 1998, 279, 548-552.
14. (c) Mokaya, R. J. Phys. Chem. B 1999, 103, 10204-10208.
15. (a) Mann, S.; Burkett, S. L.; Davis, S. A.; Fowler, C. E.; Mendelson, N. H.; Sims, S. D.; Walsh, D.; Whilton, N. T. Chem. Mater. 1997, 9, 2300-2310.
16. (b) Stein, A. Adv. Mater. 2003, 15, 763-775.