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2O and tris(N-ethylamine)amine in sufficient hot dilute (1 M) hydrochloric acid solution to completely dissolve the components. Upon cooling, red-orange crystals of the compound were obtained. Chemical analysis: C 14.41 (14.59)%; H 4.68 (4.49)%; N 10.96 (11.34)%.
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31
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3242760767
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note
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1 diffractometer, upgraded to Siemens P4 specifications, and equipped with a graphite monochromator.9 Data collection parameters and refinement results are given in the Supporting Information. Structure solutions and refinement were obtained using the SHELXTL package.10,11 Hydrogen atoms were included at calculated positions and refined assuming a riding model.
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3242799803
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2 = 0.0710.
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-
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36
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3242799031
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-
note
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Variable temperature susceptibility measurements were carried out in the temperature range 2-300 K at a magnetic field of 0.1 T on ground polycrystalline samples with a SQUID magnetometer (Quantum Design MPMS-XL-5). The susceptibility data were corrected for the diamagnetic contributions as deduced by using Pascal's constant tables and for the sample holders. Isothermal magnetization measurements were made at different temperatures, after zero field cooling, between 0 and 5 T.
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