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3242665818
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note
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2O was used.
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19
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3242696664
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note
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2- 0.25M. After 3 h of irradiation with a medium pressure Hg lamp, the reaction was quenched by the addition of MeI (6 equiv) in excess, and quantified by GC using the internal standard method.
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20
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0034741404
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22
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3242673082
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note
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o is the initial concentration of the nucleophile; ArH and ArNu are the concentrations of the reduction and substitution products at time t. These equations are based on the assumption that the reactions of the aryl radicals with the nucleophiles and the solvent are first order in the latter species, and their concentrations are constant during the experiments.
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23
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0035069478
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