Polymer electrolyte membrane fuel cell modelling: d.c. and a.c. solutions

Chemical Engineering Research and Design

Volumn 82, Issue 7, 2004, Pages 907-917

  Bautista, M ^a   Bultel, Y ^a   Ozil, P ^a  

^a LEPMI   (France)

Author keywords

Electrode; Impedance; Modelling; PEMFC; Steady state

Indexed keywords

DIFFUSION; ELECTRODES; MASS TRANSFER; MATHEMATICAL MODELS; MEMBRANES; POLYELECTROLYTES; TRANSPORT PROPERTIES;

MEMBRANE ELECTRODES; MEMBRANE FUEL CELLS;

FUEL CELLS;

ELECTROLYTE; FUEL CELL; MASS TRANSFER; MEMBRANE; MODELING;

EID: 3242735928     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1205/0263876041596742     Document Type: Article

References (26)

1. Amphlett, J.C., Mann, R.F., Peppley, B.P., Roberge, P.R. and Rodrigues, A., 1996, A model predicting transient response of proton exchange membrane fuel cells, J Power Sources, 61: 183-188.
2. Antoine, O., Bultel, Y. and Durand, R., 2001, Oxygen reduction reaction kinetic and mechanism on Platinum nanoparticles inside Nafion, J Electroanal Chem, 499: 85-94.
3. Antolini, E., Passos, R.P. and Ticianelli, E.A., 2002, Effect of the cathode gas diffusion layer characteristics on the performance of the polymer electrolyte fuel cells, J Appl Electrochem, 32: 383-388.
4. Bernardi, D.M., 1990, Water-balance calculation for solid-polymer-electrolyte fuel cells, J Electrochem Soc, 137: 3344-3350.
5. Bernardi, D.M. and Verbrugge, M.K., 1992, A mathematical model of the solid-polymer-electrolyte fuel cell, J Electrochem Soc, 139: 2477-2491.
6. Broka, K. and Ekdunge, R, 1997, Modelling the PEM fuel cell cathode, J Appl Electrochem, 27: 281-289.
7. Bultel, Y., Geniès, L., Antoine, O., Ozil, P. and Durand, R., 2002, Modelling impedance diagrams of active layers in gas diffusion electrodes: diffusion, ohmic drop effect and multistep reactions, J Electroanal Chem, 572: 143-155.
8. Bultel, Y., Jaouen, E, Ozil, P. and Lindbergh, G., 2003, Modeling of gas diffusion electrode: d.c. and a.c. models, in 203rd Meeting of the Electrochemical Society, Abstract no. 2330 (CD), April 27-May 2, Paris.
9. Dannenberg, K., Ekdunge, P. and Lindbergh, G., 2000, Mathematical model of the PEMFC, J Appl Electrochem, 30: 1377-1387.
10. Freire, T.J.P. and Gonzales, E.R., 2001, Effect of membrane characteristics and humidification conditions on the impedance response of polymer electrolyte fuel cells, J Electroanal Chem, 503: 57-68.
11. Keddam, M., Rakotomavo, C. and Takenouti, H., 1984, Impedance of a porous electrode with an axial gradient of concentration, J Appl Electrochem, 14: 437-448.
12. (R: covered platinum electrode, Electrochim Acta, 42: 1031-1039.
13. Murgia, G., Pisani, L., Valentini, M. and Aguanno, B.D., 2002, Electrochemistry and mass transport in polymer electrolyte membrane fuel cells, J Electrochem Soc, 149: A31-A38.
14. Natarajan, D. and Nguyen, T.V., 2001, A two-dimensional, two-phase, multicomponent, transient model for the cathode proton exchange membrane fuel cell using conventional gas distributor, J Electrochem Soc, 148: A1324-A1335.
15. Nguyen, T.V. and White, R.E., 1993, A water and heat management model for proton-exchange-membrane-fuel-cell, J Electrochem Soc, 140: 2178-2186.
16. R interface-a microelectrode investigation, J Electrochem Soc, 139: 2530-2537.
17. Passalacqua, E., Squadrito, G., Lufrano, F., Patti, A. and Giorgi, L., 2001, Effect of the diffusion layer characteristics on the performance of the polymer electrolyte fuel cell electrodes, J Appl Electrochem, 31: 449-454.
18. Song, J.M., Cha, S.Y. and Lee, W.M., 2001, Optimal composition of polymer electrolyte fuel cell electrodes determined by the a.c.impedance method, J Power Sources, 94: 78-84.
19. Springer, T.E. and Raistrick, I.D., 1989, Electrical impedance of a pore wall for the flooded-agglomerate model of porous gas-diffusion-electrodes, J Electrochem Soc, 136: 1594-1603.
20. Springer, T.E., Zawodzinski, T.A. and Gottesfeld, S., 1991, Polymer electrolyte fuel cell model, J Electrochem Soc, 138: 2334-2342.
21. Springer, T.E., Wilson, M.S. and Gottesfeld S., 1993, Modeling and experimental diagnostics in polymer electrolyte fuel cells, J Electrochem Soc, 140:3513-3526.
22. Springer, T.E., Zawodzinski, T.A., Wilson, M.S. and Gottesfeld, S., 1996, Characterization of polymer electrolyte fuel cells using AC impedance spectroscopy, J Electrochem Soc, 143: 587-598.
23. Um, S., Wang, CW. and Chen, K.S., 2000, Computational fluid dynamics modeling of proton exchange membrane fuel cell, J Electrochem Soc, 147:4485-4493.
24. Wagner, N., 2002, Characterization of membrane electrode assemblies in polymer electrolyte fuel cells using a.c. impedance spectroscopy, J Appl Electrochem, 32: 859-863.
25. Walkiewicz, S., Bultel, Y., Le Gorrec, B. and Diard, J.P., 2002, Modeling impedance diagrams of Fuel Cell, in 4th International Symposium on electrocatalysis, in Satellite Meeting of the 53rd ISE Meeting in Duesseeldorf, Abstract 71, 22-25 September, Como.
26. Yi, J.S. and Nguyen, T.V, 1999, Multicomponent transport in porous electrode of proton exchange membrane fuel cell using interdigitated gas distributor, J Electrochem Soc, 146: 38-45.