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Volumn 7, Issue 7, 2004, Pages 906-908

A novel perchlorate-bridged tetranuclear zinc(II) structure with tris(2-aminoethyl)amine ligand

Author keywords

Crystal structure; MNDO calculation; Perchlorate bridged; Tris(2 aminoethyl)amine; Zinc tetramer

Indexed keywords

AMINE; LIGAND; ZINC DERIVATIVE;

EID: 3242735008     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2004.05.020     Document Type: Article
Times cited : (11)

References (17)
  • 7
    • 33646669784 scopus 로고    scopus 로고
    • note
    • 2 atmosphere for slow evaporation. After a few days, a 29.9% yield of colorless cubic crystals was obtained
  • 8
    • 33646642790 scopus 로고    scopus 로고
    • note
    • -1) for title complex (KBr pressed pellet): 1600 s, 1464 s, 1318 s, 1274 s, 1077 s, 988 s, 940 m, 883 s, 745 m. 636 m
  • 9
    • 33646657738 scopus 로고    scopus 로고
    • note
    • 2=0.1678. CCDC=226369. Intensity data were collected on a Bruker CCD area detector diffractometer using graphite monochromated Mo-Kα radiation (= 0.71073 Å) from generator operating at 50 KV, 30 mA condition in the range of θ=3.53 -24.88°at 294 K. Oscillation frames of φ and ω are in the range of 0-180°. A self-consistent absorption correction of SADABS program based on Fourier coefficient fitting was applied. The crystal structure was determined by the direct method which yielded the positions of part of non-hydrogen atoms and subsequent difference Fourier syntheses were employed to locate all of the remaining non-hydrogen atoms which did not show up in the initial structure. All of non-hydrogen atoms were refined anisotropically with weight function. Hydrogen atoms were located basing on difference Fourier Syntheses connecting geometrical analysis. All experiment and computation were performed on a PC computer with program of Bruker Smart and Bruker Shelxtl package


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.